Skip to Content
Merck
CN

CN520764

Palladium(II) acetate

≥99%

Synonym(s):

Palladium(II) acetate, Pd(OAc)2, [Pd(OAc)2]3

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
Pd(OCOCH3)2
CAS Number:
3375-31-3
Molecular Weight:
224.51
NACRES:
NA.22
PubChem Substance ID:
24874166
UNSPSC Code:
12161600
MDL number:
MFCD00012453

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

SMILES string

CC(O[Pd]OC(C)=O)=O

InChI key

YJVFFLUZDVXJQI-UHFFFAOYSA-L

assay

≥99%

reaction suitability

reagent type: catalyst
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
core: palladium
reaction type: C-H Activation, reagent type: catalyst
core: palladium
reaction type: Cross Couplings, reagent type: catalyst
core: palladium
reaction type: Heck Reaction, reagent type: catalyst
core: palladium
reaction type: Hiyama Coupling, reagent type: catalyst
core: palladium
reaction type: Negishi Coupling, reagent type: catalyst
core: palladium
reaction type: Sonogashira Coupling, reagent type: catalyst
core: palladium
reaction type: Stille Coupling, reagent type: catalyst
core: palladium
reaction type: Suzuki-Miyaura Coupling

Quality Level

200

Looking for similar products? Visit Product Comparison Guide

General description

Palladium(II) acetate is a homogenous oxidation catalyst. It participates in the activation of alkenic and aromatic compounds towards oxidative inter- and intramolecular nucleophilic reactions.[] Crystals of palladium(II) acetate have a trimeric structure, having symmetry D3h. Each of the palladium atoms in the crystals are joined to the other two by double acetate bridges.[] Microencapsulation of palladium(II) acetate in polyurea affords polyurea-encapsulated palladium(II) acetate. It is a versatile heterogeneous catalyst for various phosphine-free cross-coupling reactions.[] It participates as catalyst in the Heck coupling reaction of pthalides with different alkenes.[]

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions Palladium(II) acetate was employed as a catalyst for the following reactions: 1. Formation of allylic acetates.[] (eq. 1) 2. Hydroselenation of triple bonds.[6] (eq. 2) 3. Heck arylation of alkenes.[7] (eq. 3) 4. Cyclocarbonylation.[8] (eq. 4) 5. Buchwald-Hartwig amination reaction.[9] (eq. 5) For small scale and high throughput uses, product is also available as ChemBeads (924377)(link the product#)

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1A

Storage Class

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

It looks like we've run into a problem, but you can still download Certificates of Analysis from our Documents section.

If you need assistance, please contact Customer Support

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service