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Merck
CN

97151

Hederacoside C

analytical standard

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About This Item

Empirical Formula (Hill Notation):
C59H96O26
CAS Number:
14216-03-6
Molecular Weight:
1221.38
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
329770354
EC Number:
238-072-2
Beilstein/REAXYS Number:
4229541
MDL number:
MFCD00198062

Key Documents

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Product Name

Hederacoside C, analytical standard

InChI key

RYHDIBJJJRNDSX-WBOYGZCJSA-N

InChI

1S/C59H96O26/c1-24-34(63)38(67)42(71)49(78-24)83-46-29(20-60)80-48(45(74)41(46)70)77-22-30-37(66)40(69)44(73)51(81-30)85-53(75)59-17-15-54(3,4)19-27(59)26-9-10-32-55(5)13-12-33(56(6,23-61)31(55)11-14-58(32,8)57(26,7)16-18-59)82-52-47(36(65)28(62)21-76-52)84-50-43(72)39(68)35(64)25(2)79-50/h9,24-25,27-52,60-74H,10-23H2,1-8H3/t24-,25-,27?,28-,29+,30+,31?,32+,33-,34-,35-,36-,37+,38+,39+,40-,41+,42+,43+,44+,45+,46+,47+,48+,49-,50-,51-,52-,55-,56-,57+,58+,59-/m0/s1

SMILES string

[H][C@]12CC=C3C4CC(C)(C)CC[C@@]4(CC[C@@]3(C)[C@]1(C)CCC5[C@](C)(CO)[C@H](CC[C@]25C)O[C@@H]6OC[C@H](O)[C@H](O)[C@H]6O[C@@H]7O[C@@H](C)[C@H](O)[C@@H](O)[C@H]7O)C(=O)O[C@@H]8O[C@H](CO[C@@H]9O[C@H](CO)[C@@H](O[C@@H]%10O[C@@H](C)[C@H](O)[C@@H](O)[C@H]%10O)[C@H](O)[C@H]9O)[C@@H](O)[C@H](O)[C@H]8O

grade

analytical standard

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

222 °C (dec.) (lit.)

application(s)

food and beverages

format

neat

storage temp.

2-8°C

Quality Level

100

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Application

This analytical standard can also be used as follows:
  • Development of a bioanalytical method to measure hederacoside c in rat plasma samples by ultra high-performance liquid chromatographic-tandem mass spectrometric (UPLC-MS/MS) method
  • Simultaneous analysis of six natural compounds isolated from ivy leaf extract samples by UHPLC coupled with electrospray ionization-triple quadrupole mass spectrometeric (ESI-MS/MS) detection
  • Ultra-high-performance liquid chromatography-quadrupole time-of-flight mass spectrometry (UHPLC‐Q‐TOF‐MS/MS) based phytochemical profiling of Hedera helix for pharmaceutical applications

General description

Hederacoside C is a natural triterpenoid saponin. It is the primary bioactive ingredient of traditional Chinese herbal medicines, isolated from Hedera helix, also known as common ivy or English ivy. It is known for its expectorant, bronchodilator, antibacterial, and bronchospasmolytic properties in the treatment of respiratory disorders.

Other Notes

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. The content inside is inserted in a fused cone.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000480904
0000480904
0000424501
0000424501
BCCN0474

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A validated RP HPLC-PAD method for the determination of hederacoside C in Ivy-Thyme cough syrup
Khdair A, et al.
International Journal of Analytical Chemistry (2010)
Determination of saponins and flavonoids in ivy leaf extracts using HPLC-DA
Yu M, et al.
Journal of Chromatographic Science, 53(4), 478-483 (2014)
S H Cho et al.
Archives of pharmacal research, 14(1), 19-24 (1991-03-01)
One new triterpenoidal saponin, saponin F(2) has been isolated from the bark of Kalopanax pictum Nakai var. typicum (Araliaceae), together with one known saponin, kizuta saponin K12 (1). On the basis of chemico-spectral evidences, the structure of 2 has been
W J Sun et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 25(1), 29-34 (1990-01-01)
Two crystalline components I and II were isolated from the total saponin of Kalopanax septemlobus (Thunb.) koidz. Crystalline II was identified as kalopanax saponin A and I was named as Kalopanax saponin C and eluciated as 3-O-[alpha-L-rhamnopyranosyl-(1----2)-alpha-L-arabinopyranosyl]- hedragenin-28-[alpha-L-rhamnopyranosyl-(1----2)- beta-D-glucopyranosyl (1----6)-beta-D-glucopyransyl]ester
Jongwon Choi et al.
Journal of ethnopharmacology, 79(2), 199-204 (2002-01-22)
In the present study, we have attempted to elucidate the active components for rheumatoidal arthritis using chloroform (CHCl(3)), ethylacetate (EtOAc) and n-butanol (BuOH) fractions of the methanol extract (MeOH) of Kalopanax pictus. Kalopanaxsaponin-A and -I (KPS-A and -I, hederagenin monodesmoside)
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