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Merck
CN

95159

Ferrocenecarboxaldehyde

for HPLC derivatisation, LiChropur™, ≥98.0% (HPLC)

Synonym(s):

Cyclopentadienyl(formylcyclopentadienyl)iron

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About This Item

Empirical Formula (Hill Notation):
C11H10FeO
CAS Number:
12093-10-6
Molecular Weight:
214.04
NACRES:
NA.22
PubChem Substance ID:
329770425
UNSPSC Code:
12352200
EC Number:
235-158-1
MDL number:
MFCD00001429

Key Documents

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Product Name

Ferrocenecarboxaldehyde, for HPLC derivatisation, LiChropur™, ≥98.0% (HPLC)

InChI key

UQTCQJVPLIVCAX-UHFFFAOYSA-N

InChI

1S/C6H5O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-5H;1-5H;

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.[H]C(=O)[C]2[CH][CH][CH][CH]2

assay

≥98.0% (HPLC)

form

crystals

quality

LiChropur™

mp

118-120 °C (lit.)

Quality Level

100

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Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCBZ5147
BCBX0729
BCBT0478

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Mina Okochi et al.
Biotechnology and bioengineering, 90(1), 14-19 (2005-03-01)
Labeling of ferrocenecarboaldehyde (Fc-CHO) to immunoglobulin G (IgG) via formation of Schiff-base and its reduction was investigated for construction of an electrochemical probe for miniaturized amperometric flow immunoassay. Approximately eight molecules of Fc-CHO were labeled to IgG and the reversible
C Xu et al.
Fresenius' journal of analytical chemistry, 367(6), 593-595 (2001-02-28)
A ferrocenecarboxaldehyde (FCA) labeled DNA probe is used for the first time in the study of DNA damage and protection. The electrochemically active reagent FCA was labeled successfully on to a denatured calf-thymus DNA by 1-ethyl-3- (3-dimethyl-aminopropyl) carbodiimide (EDC). The
Kubab, N., et al.
Analusis, 17, 559-564 (1989)
John Spencer et al.
Dalton transactions (Cambridge, England : 2003), (6)(6), 918-921 (2009-01-29)
The Knoevenagel condensation of 1,3-dihydro-2H-indol-2-one with ferrocene carboxaldehyde afforded an approximate 2:1 mixture of the geometrical isomers (E)- and (Z)-3-ferrocenylmethylidene-1,3-dihydro-2H-indol-2-one respectively in an overall 67% yield; the air and solution-stable isomers were readily separated by preparative thin layer chromatography and
Zhipeng Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 27(4), 1286-1291 (2010-11-04)
Single-component microcapsules were fabricated by the in situ reaction of ferrocenecarboxaldehyde (Fc-CHO) with poly(allylamine hydrochloride) (PAH) doped inside CaCO(3) microparticles, followed by core removal. The PAH-Fc microcapsules had very thick shells with remnant PAH-Fc inside, leading to a robust capsule
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