All Photos(1)
Synonym(s):
2,2′-Thiobis(ethanol), Bis(2-hydroxyethyl) sulfide, Thiodiethylene glycol, Thiodiglycol
Linear Formula:
S(CH2CH2OH)2
CAS Number:
Molecular Weight:
122.19
Beilstein:
1236325
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
purum
Quality Level
Assay
≥95.0% (GC)
form
liquid
refractive index
n20/D 1.521
n20/D 1.5215 (lit.)
bp
164-166 °C/20 mmHg (lit.)
mp
−16 °C (lit.)
density
1.221 g/mL at 25 °C (lit.)
SMILES string
OCCSCCO
InChI
1S/C4H10O2S/c5-1-3-7-4-2-6/h5-6H,1-4H2
InChI key
YODZTKMDCQEPHD-UHFFFAOYSA-N
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Application
2,2′-Thiodiethanol is used in the preparation of a wide range of gold complexes, which include Au(I) based catalysts such as chloro(triphenylphosphine)gold(I) [Au(PPh3)Cl], chloro(dimethyl sulfide)gold(I) [Au(SMe2)Cl] and chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) [IPrAuCl]. It can also be used to build calixarene frameworks.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2
WGK
WGK 1
Flash Point(F)
closed cup
Flash Point(C)
closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
监管及禁止进口产品
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Find documentation for the products that you have recently purchased in the Document Library.
Gold (I)?Catalyzed Intermolecular Cyclopropanation of Enynes with Alkenes: Trapping of Two Different Gold Carbenes.
Lopez S, et al.
Angewandte Chemie (International Edition in English), 118(36), 6175-6178 (2006)
Stereo-and regioselective gold-catalyzed hydroamination of internal alkynes with dialkylamines.
Hesp K D, et al.
Journal of the American Chemical Society, 132(51), 18026-18029 (2010)
Networking of calixcrowns: From heteronuclear endo/exocyclic coordination polymers to a photoluminescence switch.
Lee J Y, et al.
Journal of the American Chemical Society, 130(42), 13838-13839 (2008)
A general synthesis for gold (I) complexes.
Al?Sa'Ady A K, et al.
Inorg. Synth., 23, 191-194 (1985)
Binding and extraction of alkali and alkaline earth metals by nano-baskets of calix [4] arene-1, 2-crown-3.
Mokhtari B and Pourabdollah K
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 73(1-4), 269-277 (2012)
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