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74867

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Dichlorvos-(dimethyl-d6)

PESTANAL®, analytical standard

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Synonym(s):
2,2-Dichlorovinyl di(methyl-d3) phosphate, Dichlorvos-d6
Empirical Formula (Hill Notation):
C4D6HCl2O4P
CAS Number:
203645-53-8
Molecular Weight:
227.01
MDL number:
MFCD00209708
UNSPSC Code:
77101502
PubChem Substance ID:
329765923
NACRES:
NA.24

grade

analytical standard

Quality Level

100

isotopic purity

≥95.0 atom % D

product line

PESTANAL®

Assay

≥98.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture
environmental

format

neat

storage temp.

−20°C

SMILES string

ClC(Cl)=COP(OC([2H])([2H])[2H])(OC([2H])([2H])[2H])=O

InChI

1S/C4H7Cl2O4P/c1-8-11(7,9-2)10-3-4(5)6/h3H,1-2H3/i1D3,2D3

InChI key

OEBRKCOSUFCWJD-WFGJKAKNSA-N

Related Categories

General description

Dichlorvos-(dimethyl-d6) is an isotope labeled analog of the organophosphate insecticide dichlorvos, wherein the dimethoxy protons are replaced by deuterium.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The major advantage of using this technique is that the isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analogs, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis, potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

closed cup

Flash Point(C)

closed cup

Regulatory Information

危险化学品

Certificates of Analysis (COA)

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Semiconductor-sensitized photodegradation of dichlorvos in water using TiO2 and ZnO as catalysts
Evgenidou E, et al.
Applied Catalysis. B, Environmental, 59(1-2), 81-89 (2005)

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