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Merck
CN

69692

3-Buten-2-one

purum, ≥95.0% (GC)

Synonym(s):

Methyl vinyl ketone, Vinyl methyl ketone

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About This Item

Linear Formula:
CH2=CHCOCH3
CAS Number:
Molecular Weight:
70.09
EC Number:
201-160-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
506021
MDL number:
Assay:
≥95.0% (GC)
Form:
liquid
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InChI key

FUSUHKVFWTUUBE-UHFFFAOYSA-N

InChI

1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3

SMILES string

CC(=O)C=C

vapor density

1.3 (vs air)

vapor pressure

310 mmHg ( 55 °C), 71 mmHg ( 20 °C)

grade

purum

assay

≥95.0% (GC)

form

liquid

contains

~0.5% acetic acid as stabilizer, ~0.5% hydroquinone as stabilizer

expl. lim.

15.64 %

impurities

~5% water

Quality Level

refractive index

n20/D 1.412

bp

81 °C (lit.)

density

0.86 g/mL at 20 °C, 0.864 g/mL at 25 °C (lit.)

storage temp.

2-8°C

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Disclaimer

may discolor to brown on storage

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

19.4 °F - closed cup

flash_point_c

-7 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Regulatory Information

监管及禁止进口产品
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Ying Liu et al.
Environmental science & technology, 43(1), 75-81 (2009-02-13)
It is important to identify the sources of reactive volatile organic compounds (VOCs) in Beijing for effective ground-level ozone abatement. In this paper, semihourly measurements of hydrocarbons and oxygenated VOCs (OVOCs) were taken at an urban site in Beijing in
Paul Schweiger et al.
Applied microbiology and biotechnology, 80(6), 995-1006 (2008-07-17)
Three cytosolic NADPH-dependent flavin-associated proteins (Gox2107, Gox0502, and Gox2684) from Gluconobacter oxydans 621H were overproduced in Escherichia coli, and the recombinant enzymes were purified and characterized. Apparent native molecular masses of 65.2, 78.2, and 78.4 kDa were observed for Gox2107
David Rabuka et al.
Journal of the American Chemical Society, 130(18), 5947-5953 (2008-04-12)
The controlled addition of structurally defined components to live cell membranes can facilitate the molecular level analysis of cell surface phenomena. Here we demonstrate that cell surfaces can be engineered to display synthetic bioactive polymers at defined densities by exogenous
Christopher J Martyniuk et al.
Chemical research in toxicology, 24(12), 2302-2311 (2011-11-17)
α,β-Unsaturated carbonyls make up an important class of chemicals involved in environmental toxicity and disease processes. Whereas adduction of cysteine residues on proteins is a well-documented reaction of these chemicals, such a generic effect cannot explain the molecular mechanism of
José M Aurrecoechea et al.
The Journal of organic chemistry, 73(9), 3650-3653 (2008-03-28)
Palladium-catalyzed heterocyclization-coupling sequences have been developed starting from buta-1,2,3-trienyl carbinols and electron-deficient alkenes. Polysubstituted furans are formed where the heterocyclic ring originates from the elements of the butatrienyl carbinol while the electron-deficient olefin is incorporated as a C-3 substituent. In

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