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67870

Sigma-Aldrich

4-Methylmorpholine

purum, ≥98.0% (GC)

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Synonym(s):
N-Methylmorpholine, NMM
Empirical Formula (Hill Notation):
C5H11NO
CAS Number:
109-02-4
Molecular Weight:
101.15
Beilstein:
102719
EC Number:
203-640-0
MDL number:
MFCD00006175
UNSPSC Code:
12352100
PubChem Substance ID:
329760698
NACRES:
NA.22

vapor density

>1 (vs air)

Quality Level

200

vapor pressure

18 mmHg ( 20 °C)

grade

purum

Assay

≥98.0% (GC)

refractive index

n20/D 1.435 (lit.)
n20/D 1.435

bp

115-116 °C/750 mmHg (lit.)

mp

−66 °C (lit.)

density

0.918 g/mL at 20 °C
0.92 g/mL at 25 °C (lit.)

SMILES string

CN1CCOCC1

InChI

1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3

InChI key

SJRJJKPEHAURKC-UHFFFAOYSA-N

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Application

4-Methylmorpholine(NMM) has been used for amidation of hyaluronic acid to synthesize its derivative with potential applications in hydrogel synthesis and gold coatings.
NMM can be used as a reactant for the synthesis of:
  • 1-Butyl-1-methylmorpholinium bromide ([BMmo][Br]), a monocation ionic liquid.
  • Quaternary ammonium complexes that can be used as complexing agents in redox flow batteries (RFBs).

It can also be used as an activating reagent:
  • For the synthesis of peptide-drug conjugate for targeted drug delivery.
  • To synthesize acrylate star polymers with application as magnetic resonance imaging (MRI) agents.

Signal Word

Danger

Hazard Statements

H225,H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

WGK

WGK 1

Flash Point(F)

DIN 51755 Part 1

Flash Point(C)

DIN 51755 Part 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Relationship between the Structure of Ionic Liquid and Its Enrichment Ability To Trace Fungicides from an Environmental Water Sample.
Yang J, et al.
Journal of Agricultural and Food Chemistry, 66(36), 9418-9425 (2018)
Complexing Additives to Reduce the Immiscible Phase Formed in the Hybrid ZnBr2 Flow Battery.
Bryans D, et al.
Journal of the Electrochemical Society, 164(13), A3342-A3348 (2017)
A Peptide-Guided System with Programmable Subcellular Translocation for Targeted Therapy and Bypassing Multidrug Resistance.
Zhu Y, et al.
Analytical Chemistry, 164(13), A3342-A3348 (2018)
High relaxivity MRI imaging reagents from bimodal star polymers.
Adkins CT, et al.
Polym. Chem., 3(2), 390-398 (2012)
Investigating triazine-based modification of hyaluronan using statistical designs.
Liang J, et al.
Carbohydrate Polymers, 132, 472-480 (2015)
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