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63677

Supelco

(−)-Menthone

analytical standard

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Synonym(s):
(1R,4S)-p-Menthan-3-one, (2S,5R)-2-Isopropyl-5-methylcyclohexanone
Empirical Formula (Hill Notation):
C10H18O
CAS Number:
Molecular Weight:
154.25
Beilstein:
2041368
EC Number:
MDL number:
UNSPSC Code:
85151701
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor pressure

0.5 mmHg ( 20 °C)

Assay

≥98.5% (sum of enantiomers, GC)

optical activity

[α]20/D −28±2°, neat

optical purity

enantiomeric ratio: ≥90:10 (GC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.45 (lit.)
n20/D 1.451

bp

207-210 °C (lit.)

density

0.893 g/mL at 20 °C (lit.)

application(s)

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care

format

neat

storage temp.

2-8°C

SMILES string

CC(C)[C@@H]1CC[C@@H](C)CC1=O

InChI

1S/C10H18O/c1-7(2)9-5-4-8(3)6-10(9)11/h7-9H,4-6H2,1-3H3/t8-,9+/m1/s1

InChI key

NFLGAXVYCFJBMK-BDAKNGLRSA-N

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Highly purified (-)-menthone. Resolving agent for diols via acetalization ; Menthone-derived spirocyclic 1,3-dioxane-4,6-diones are used in asymmetric Diels-Alder and (2+2) cycloadditions

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Skin Irrit. 2 - Skin Sens. 1

WGK

WGK 1

Flash Point(F)

165.2 °F

Flash Point(C)

74 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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M. Sato et al.
Tetrahedron, 47, 7271-7271 (1991)

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