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Merck
CN

60591

Potassium tetrakis(4-chlorophenyl)borate

Selectophore, ≥98.0%

Synonym(s):

Tetrakis(4-chlorophenyl)boron potassium

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About This Item

Linear Formula:
(ClC6H4)4BK
CAS Number:
Molecular Weight:
496.11
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
EC Number:
238-723-0
Beilstein/REAXYS Number:
4117827
MDL number:
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Product Name

Potassium tetrakis(4-chlorophenyl)borate, Selectophore, ≥98.0%

InChI key

SAGICZRAKJSWLD-UHFFFAOYSA-N

InChI

1S/C24H16BCl4.K/c26-21-9-1-17(2-10-21)25(18-3-11-22(27)12-4-18,19-5-13-23(28)14-6-19)20-7-15-24(29)16-8-20;/h1-16H;/q-1;+1

SMILES string

[K+].Clc1ccc(cc1)[B-](c2ccc(Cl)cc2)(c3ccc(Cl)cc3)c4ccc(Cl)cc4

description

for ion-selective electrodes

product line

Selectophore

assay

≥98.0% (AT)
≥98.0%

form

solid

Quality Level

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Application

Potassium tetrakis(4-chlorophenyl)borate was used as lipophilic anionic site in constructing fluorescent optode for sodium. It was also used as coating for the piezoelectric crystal in quantifying Potassium using quartz crystal microbalance.

General description

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Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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B D Pendley et al.
Analytical chemistry, 73(19), 4599-4606 (2001-10-19)
A new chronoamperometric method is used to estimate changes in the membrane composition of mobile-site, ionophore-based membranes. The characteristic features of the chronoamperometric curves (initial current, slope, break time) of valinomycin-based, potassium-selective membranes loaded with potassium tetrakis(4-chlorophenyl)borate are correlated with
Larisa Lvova et al.
Sensors (Basel, Switzerland), 13(5), 5841-5856 (2013-05-09)
5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin
Qianyu Zhang et al.
Sensors (Basel, Switzerland), 13(6), 6936-6945 (2013-05-28)
A flow biosensor for the detection of toxicity in water using the ammonia-oxidizing bacterium (AOB) Nitrosomonas europaea as a bioreceptor and a polymeric membrane ammonium-selective electrode as a transducer is described. The system is based on the inhibition effects of
X Yang et al.
Talanta, 52(6), 1033-1039 (2008-10-31)
A fluorescent optode membrane for sodium ion that works on the basis of a cation-exchange mechanism has been developed. The plasticized poly(vinyl chloride) (PVC) membrane incorporating sodium-selective ionophore (4-tert-butylcalix[4]arene tetraacetic acid tetraethyl ester), acidic fluorescent pH indicator (5,10,15,20-tetraphenylporphine, TPP) and
Konrad Rudnicki et al.
Analytica chimica acta, 1085, 75-84 (2019-09-17)
In this paper, the electrochemical behavior of four fluoroquinolone antibiotics (FAs) [Ciprofloxacin (Cip), Enrofloxacin (Enr), Marbofloxacin (Mar) and Ofloxacin (Ofl)] at a polarized interface between two immiscible electrolyte solutions (ITIES) has been studied using ion-transfer voltammetry (ITV). The measurements were

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