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56257

Supelco

Ferroceneboronic acid

for HPLC derivatization, LiChropur™, ≥97.0% (HPLC)

Synonym(s):

(Boronocyclopentadienyl)cyclopentadienyl iron, NSC 119337

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About This Item

Empirical Formula (Hill Notation):
C10H11BFeO2
CAS Number:
12152-94-2
Molecular Weight:
229.85
EC Number:
235-272-1
MDL number:
MFCD00059074
UNSPSC Code:
12000000
PubChem Substance ID:
329758194
NACRES:
NA.22

grade

for HPLC derivatization

Quality Level

100

Assay

≥97.0% (HPLC)

quality

LiChropur™

reaction suitability

reagent type: catalyst
core: iron

technique(s)

HPLC: suitable

mp

145-150 °C (dec.) (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.OB(O)[C]2[CH][CH][CH][CH]2

InChI

1S/C5H6BO2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4,7-8H;1-5H;

InChI key

HHGAJIKAUQWFKH-UHFFFAOYSA-N

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Application

Redox-acitce electrochemical probe to monitor interactions involving sugars

Reactant involved in:
  • Synthesis of ferrocene-appended subporphyrins for electrochemical property studies
  • Synthesis of catalysts for polymerization of olefins
  • Suzuki-coupling reaction with organic triflates
  • Catalytic ortho-lithiation
Derivatization reagent for the determination of brassinosteroids

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Contains varying amounts of anhydride

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC6128
BCBW6087
BCBS0702V

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Keiji Gamoh, K., et al.
Journal of Chromatography A, 515, 227-231 (1990)
Artur Kasprzak et al.
Carbohydrate polymers, 198, 294-301 (2018-08-11)
Interactions of select boric acid derivatives with β-cyclodextrin were investigated. All products were obtained employing the grinding-induced mechanochemical approach. It was found that phenylboronic acid, benzoxaborole and boric acid form non-covalent, hydrogen bonding-based systems with β-cyclodextrin, whereas catechol and pinacol

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