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Key Documents

Safety Information

537446

Sigma-Aldrich

Ethyl acetate

ReagentPlus®, ≥99.8%

Synonym(s):

EtOAc

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18 L
¥3,876.66

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18 L
¥3,876.66

About This Item

Linear Formula:
CH3COOC2H5
CAS Number:
Molecular Weight:
88.11
Beilstein:
506104
EC Number:
MDL number:
UNSPSC Code:
12352108
PubChem Substance ID:
NACRES:
NA.21

bp:
76.5-77.5 °C (lit.)
vapor pressure:
73 mmHg ( 20 °C)

¥3,876.66


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vapor density

3 (20 °C, vs air)

Quality Level

vapor pressure

73 mmHg ( 20 °C)

product line

ReagentPlus®

Assay

≥99.8%

form

liquid

autoignition temp.

801 °F

expl. lim.

2.2-11.5 %, 38 °F

dilution

(for general lab use)

impurities

≤0.003 mg/mL non-volatile matter
≤0.02% Ethyl alcohol
≤0.05% water

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This Item
437549319902650528
assay

≥99.8%

assay

≥99.5%

assay

≥99.5%

assay

99.9%

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

solubility

alcohol: soluble(lit.), water: soluble, chloroform: soluble(lit.)

solubility

alcohol: soluble(lit.), chloroform: soluble in salt form(lit.)

solubility

-

solubility

alcohol: soluble(lit.), chloroform: soluble(lit.)

form

liquid

form

liquid

form

liquid

form

liquid

bp

76.5-77.5 °C (lit.)

bp

76.5-77.5 °C (lit.)

bp

76.5-77.5 °C (lit.)

bp

76.5-77.5 °C (lit.)

autoignition temp.

801 °F

autoignition temp.

801 °F

autoignition temp.

801 °F

autoignition temp.

801 °F

General description

Ethyl acetate, a carboxylate ester, is bio-friendly organic solvent with wide range of industrial applications.[1] Its synthesis by reactive distillation[2][3] and by acceptorless dehydrogenative dimerization of ethanol has been explored.[4] Its utility as a less toxic alternative to diethyl ether in the formalin-ether (F-E) sedimentation procedure for intestinal parasites has been investigated.[5] Its ability as an acyl acceptor in the immobilized lipase-mediated preparation of biodiesel from crude vegetable oils has been examined.[6] The complete degradation of ethyl acetate to CO2 using manganese octahedral molecular sieve (OMS-2) has been investigated.[7]

Application

Ethyl acetate may be used in the following processes:
  • Preparation of thin films of TiO2 (titanium dioxide) on glass.[8]
  • As an extraction medium in the multi-residue analysis of pesticide residues in fruit and vegetables.[9]
  • Acetylation of primary amines to form amides in the presence of dimethyltin(IV) acetic acid distannoxane.[10]
Meets urethane grade requirements (H2O ≤ 0.05%)

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

24.8 °F - closed cup

Flash Point(C)

-4 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Christer Jansson et al.
Journal of chromatography. A, 1023(1), 93-104 (2004-02-06)
A new multi-residue method for determination of pesticide residues in a wide variety of fruit and vegetables, using the National Food Administration (NFA) ethyl acetate extraction and determination by means of LC-MS/MS, is presented. The method includes pesticides normally detected
Anatase thin films on glass from the chemical vapor deposition of titanium (IV) chloride and ethyl acetate.
O'Neill SA, et al.
Chemistry of Materials, 15(1), 46-50 (2003)
Perspectives for the biotechnological production of ethyl acetate by yeasts.
Loser C, et al.
Applied Microbiology and Biotechnology, 98(12), 5397-5415 (2014)
Manganese oxide OMS-2 as an effective catalyst for total oxidation of ethyl acetate.
Gandhe AR, et al.
Applied Catalysis. B, Environmental, 72(1), 129-135 (2007)
Catalytic Acetylation Amines with Ethyl Acetate.
Camacho-Camacho C, et al.
Main Group Metal Chemistry, 31(1-2), 13-20 (2008)

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