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Merck
CN

50463

4,N,N-Trimethylaniline

puriss., ≥99.0% (GC)

Synonym(s):

4-Dimethylaminotoluene, N,N-Dimethyl-p-toluidine

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About This Item

Linear Formula:
CH3C6H4N(CH3)2
CAS Number:
Molecular Weight:
135.21
EC Number:
202-805-4
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
774409
MDL number:
Assay:
≥99.0% (GC)
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InChI key

GYVGXEWAOAAJEU-UHFFFAOYSA-N

InChI

1S/C9H13N/c1-8-4-6-9(7-5-8)10(2)3/h4-7H,1-3H3

SMILES string

CN(C)c1ccc(C)cc1

vapor density

>1 (vs air)

grade

puriss.

assay

≥99.0% (GC)

expl. lim.

7 %

refractive index

n20/D 1.546 (lit.), n20/D 1.547

bp

211 °C (lit.), 90-92 °C/10 mmHg (lit.)

density

0.937 g/mL at 25 °C (lit.)

Quality Level

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Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Disclaimer

may discolor to yellowish-green on storage

pictograms

Skull and crossbonesHealth hazard

signalword

Danger

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

flash_point_f

168.8 °F - closed cup

flash_point_c

76 °C - closed cup

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Carc. 1B - Repr. 2 - Skin Sens. 1 - STOT RE 2

target_organs

Respiratory Tract,Blood

Regulatory Information

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Y Nomura et al.
Journal of materials science. Materials in medicine, 17(1), 29-32 (2006-01-04)
The polymerization initiators for resins cured using visible light usually consist of a photosensitizer, primarily camphorquinone (CQ), and a reducing agent, which is often a tertiary amine (DMPT, DMAEMA), while the initiator used for self-curing resins consists of benzoyl peroxide
M Noda et al.
Journal of biomedical materials research. Part A, 83(1), 123-129 (2007-03-27)
Resin composites are widely used in dentistry, and are polymerized in situ using a blue-light activated, free-radical polymerization mechanism. Blue light (400-500nm) is used to activate camphoroquinone (CQ), which decomposes to form free radicals that are stabilized by dimethyl-p-toludine (DMPT).
Anuradha Prakki et al.
Dental materials : official publication of the Academy of Dental Materials, 25(1), 26-32 (2008-09-02)
The purpose of this study was to evaluate the effect of two additives, propionaldehyde/aldehyde or 2,3-butanedione/diketone, on mechanical properties of Bis-GMA-based composites containing TEGDMA, propoxylated Bis-GMA (CH(3)Bis-GMA) or propoxylated fluorinated Bis-GMA (CF(3)Bis-GMA). Three control composites, Bis-GMA/diluent monomer (25/75 mol%), and
Yi-Ching Li et al.
Journal of biomedical materials research. Part B, Applied biomaterials, 82(1), 23-28 (2006-10-17)
Camphorquinone (CQ) is widely used as an initiator in modern visible-light (VL) cured resin systems. CQ is also characterized as a potential allergenic compound. To date, there is growing concern that CQ may produce genetic damage by inducing mutation. In
Chiemi Hirabayashi et al.
Dental materials journal, 21(4), 314-321 (2003-03-01)
Polymerization characteristics of poly (methyl methacrylate)(PMMA)/(methyl methacrylate) (MMA) resin initiated by tributylborane (TBB) were compared with those by benzoyl peroxide (BPO)/N,N-dimethyl-p-toluidine and camphorquinone (CQ)/N,N-dimethylaminoethyl methacrylate from the aspects of temporal changes of residual MMA and molecular weight up to 4

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