49298
Carbendazim-(ring-4,5,6,7-d4)
PESTANAL®, analytical standard
Synonym(s):
Methyl 2-benzimidazole-4,5,6,7-d4-carbamate
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About This Item
Empirical Formula (Hill Notation):
C9D4H5N3O2
CAS Number:
Molecular Weight:
195.21
MDL number:
UNSPSC Code:
77101502
PubChem Substance ID:
NACRES:
NA.24
Recommended Products
grade
analytical standard
Quality Level
isotopic purity
≥98 atom % D
product line
PESTANAL®
Assay
≥95.0% (HPLC)
shelf life
limited shelf life, expiry date on the label
application(s)
agriculture
environmental
format
neat
storage temp.
2-8°C
SMILES string
[2H]C1=C2C(NC(NC(OC)=O)=N2)=C([2H])C([2H])=C1[2H]
InChI
1S/C9H9N3O2/c1-14-9(13)12-8-10-6-4-2-3-5-7(6)11-8/h2-5H,1H3,(H2,10,11,12,13)/i2D,3D,4D,5D
InChI key
TWFZGCMQGLPBSX-QFFDRWTDSA-N
General description
Carbendazim is a systemic benzimidazole fungicide that targets a broad spectrum of fungi pathogens through inhibition of mitotic microtubule formation and cell division.
Carbendazim is not approved in the European Union.
Carbendazim has to be monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin. Maximum residue levels (MRLs) have been set according to Reg (EU) No 559/2011 for Carbendazim for various products of plant and animal origin from 0.01 to 2 mg/kg.
Carbendazim is widely applied in agriculture, horticulture, forest, and gardening to protect plants such as banana, mango, strawberries, oranges, pineapples, pomes, cereals, sugar beet, fodder beet, rapeseed, ornamental plants, medicinal herbs, and turf grasses. In addition, carbendazim is also used in the paint, textile, paper, and leather industries. Due to its severe toxicity and long-term retention in nature, carbendazim is banned in Australia, most of the European Union (EU), and USA.
Carbendazim was first included in Annex I to Directive 91/414/EEC in 2006 by Commission Directive 2006/135/EC. The MRLs of carbendazim in the EU, Japan, and China were 0.1 mg/kg, 10 mg/kg, and 5 mg/kg, respectively.
Carbendazim is not approved in the European Union.
Carbendazim has to be monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin. Maximum residue levels (MRLs) have been set according to Reg (EU) No 559/2011 for Carbendazim for various products of plant and animal origin from 0.01 to 2 mg/kg.
Carbendazim is widely applied in agriculture, horticulture, forest, and gardening to protect plants such as banana, mango, strawberries, oranges, pineapples, pomes, cereals, sugar beet, fodder beet, rapeseed, ornamental plants, medicinal herbs, and turf grasses. In addition, carbendazim is also used in the paint, textile, paper, and leather industries. Due to its severe toxicity and long-term retention in nature, carbendazim is banned in Australia, most of the European Union (EU), and USA.
Carbendazim was first included in Annex I to Directive 91/414/EEC in 2006 by Commission Directive 2006/135/EC. The MRLs of carbendazim in the EU, Japan, and China were 0.1 mg/kg, 10 mg/kg, and 5 mg/kg, respectively.
Application
The analytical standard can be used for the following:
- Systemic evaluation of the residue and the health risk of carbendazim from the tea garden to brewed tea
- Analysis of carbendazim in a major European river, effluents discharge and assessing the potential sources of carbendazim in the aqueous environment
- Voltammetric determination of carbendazim in orange juice by glassy carbon electrode modified with hybrid material
- To assess and compare the differential influence of tebuconazole and carbendazim, individually and combined, on soil microbial activity
- Quantitative detection of carbendazim in citrus fruit and cabbage samples by a photothermal assay based on a thermometer readout
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 1B - Repr. 1B - Skin Sens. 1
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Individual and combined effects of tebuconazole and carbendazim on soil microbial activity
Wang C, et al.
Soil Biology and Biochemistry, 6-13 null
Toxicity, monitoring and biodegradation of the fungicide carbendazim
Singh S, et al.
Environmental Chemistry Letters, 317?329 null
Li Zhou et al.
Journal of the science of food and agriculture, 98(14), 5329-5334 (2018-04-16)
Carbendazim (methyl 1H-benzimidazol-2-ylcarbamate) residue in tea is a public concern. The large gap in the maximum residue limits (MRLs) for carbendazim in tea makes it difficult to conduct pesticide management. Therefore, a systemic evaluation of the residue and the health
Sylvain Merel et al.
Environmental pollution (Barking, Essex : 1987), 239, 512-521 (2018-04-24)
Carbendazim is a fungicide commonly used as active substance in plant protection products and biocidal products, for instance to protect facades of buildings against fungi. However, the subsequent occurrence of this fungicide and potential endocrine disruptor in the aqueous environment
Giulia Bellisai et al.
EFSA journal. European Food Safety Authority, 19(8), e06773-e06773 (2021-09-02)
In compliance with Article 43 of Regulation (EC) No 396/2005, EFSA received from the European Commission a mandate to provide its reasoned opinion on the toxicological properties and maximum residue levels (MRLs) for the benzimidazole substances carbendazim and thiophanate-methyl. Specifically
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