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46917

Supelco

9-Fluorenylmethyl carbazate

for HPLC derivatization, LiChropur™, ≥99.0%

Synonym(s):

Fmoc-hydrazide

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About This Item

Empirical Formula (Hill Notation):
C15H14N2O2
CAS Number:
35661-51-9
Molecular Weight:
254.28
Beilstein:
2470262
MDL number:
MFCD00239419
UNSPSC Code:
12000000
PubChem Substance ID:
329757264
NACRES:
NA.22

grade

for HPLC derivatization

Quality Level

100

Assay

≥99.0% (HPLC)
≥99.0%

quality

LiChropur™

technique(s)

HPLC: suitable

mp

~170 °C (dec.)

fluorescence

λex 264 nm; λem 309 nm in methanol
λex 270 nm; λem 320 nm (Saccharide adducts)

storage temp.

2-8°C

SMILES string

NNC(=O)OCC1c2ccccc2-c3ccccc13

InChI

1S/C15H14N2O2/c16-17-15(18)19-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9,16H2,(H,17,18)

InChI key

YGCGPEUVGHDMLO-UHFFFAOYSA-N

Application

9-Fluorenylmethyl carbazate may be used as a derivatization reagent to derivatize progesterone for high-performance liquid chromatography, in the analysis of progesterone, 17-hydroxyprogesterone and other 3-keto steroids.It may also be used as one of the fluorescence labeling agent for high-performance liquid chromatography determination of neutral and amino monosaccharides in glycoproteins by ultraviolet and fluorescence detection.

Other Notes

Reagent for the sensitive fluorogenic derivatization of carbohydrates

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Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315 - H319 - H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCBQ9952V
BCBF1215V
1361722
013926/1
062748/1

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Determination of progesterone and 17-hydroxyprogesterone by high performance liquid chromatography after pre-column derivatization with 4, 4-difluoro-5, 7-dimethyl-4-bora-3a, 4a-diaza-s-indacene-3-propionohydrazide.
Katayama M, et al.
Analyst, 123(11), 2339-2342 (1998)
Journal of Chromatography A, 646, 45-45 (1993)
High-performance liquid chromatographic determination of neutral and amino monosaccharides by ultraviolet and fluorescence detection of sugar 9-fluoroenylmethoxycarbonyl hydrazones and 9-fluoroenylmethoxycarbonyl amino sugars at picomole and sub-picomole levels.
Zhang R, et al.
Journal of Chromatography A, 646(1), 45-52 (1993)
R E Zhang et al.
Analytical biochemistry, 195(1), 160-167 (1991-05-15)
A new derivatization reagent, Fmoc-hydrazine, has been synthesized from the reaction of Fmoc-chloroformate with hydrazine as a precolumn fluorometric labeling reagent for reducing sugars such as glucose, galactose, mannose, fructose, fucose, ribose, xylose, arabinose, lactose, and maltose. The optimization of
Jinmao You et al.
Analytica chimica acta, 636(1), 95-104 (2009-02-24)
A pre-column derivatization method for the sensitive determination of aldehydes using the tagging reagent 2-[2-(7H-dibenzo[a,g] carbazol-7-yl)-ethoxy] ethyl carbonylhydrazine (DBCEEC) followed by high-performance liquid chromatography with fluorescence detection and APCI-MS identification has been developed. The chromophore of fluoren-9-methoxy-carbonylhydrazine (Fmoc-hydrazine) reagent was
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