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Merck
CN

46443

Spiroxamine

PESTANAL®, analytical standard

Synonym(s):

N-Ethyl-N-propyl-8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-ylmethylamine

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About This Item

Empirical Formula (Hill Notation):
C18H35NO2
CAS Number:
118134-30-8
Molecular Weight:
297.48
NACRES:
NA.24
PubChem Substance ID:
329757187
UNSPSC Code:
41116107
MDL number:
MFCD03095708

Key Documents

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Product Name

Spiroxamine, PESTANAL®, analytical standard

InChI

1S/C18H35NO2/c1-6-12-19(7-2)13-16-14-20-18(21-16)10-8-15(9-11-18)17(3,4)5/h15-16H,6-14H2,1-5H3

SMILES string

CCCN(CC)CC1COC2(CCC(CC2)C(C)(C)C)O1

InChI key

PUYXTUJWRLOUCW-UHFFFAOYSA-N

grade

analytical standard

description

mixture of diastereomers

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Spiroxamine may be used as a reference standard for the determination of spiroxamine in honeybees during the honeybee poisoning incidents using gas chromatography coupled with tandem mass spectrometry (GC–MS/MS).

General description

Spiroxamine belongs to the class of spiroketalamines. It is widely used as a broad-spectrum fungicide in cereals and grapes with selective, protective, curative and eradicative properties against powdery mildew.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2

target_organs

Eyes

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

296.6 °F

flash_point_c

147 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM3577
BCCK2858
BCBZ9056

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Frédéric Suffert et al.
Microbial ecology, 77(1), 110-123 (2018-06-08)
This study provides empirical evidence for antagonistic density dependence mechanisms driving sexual reproduction in the wheat fungal pathogen Zymoseptoria tritici. Biparental crosses with 12 increasing inoculum concentrations, in controlled conditions, showed that sexual reproduction in Z. tritici was impacted by
Hydrolysis study and extraction of spiroxamine from soils of different physico-chemical properties.
Rosales-Conrado N.
Chemosphere, 77(6), 821-828 (2009)
Małgorzata Baćmaga et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 54(4), 252-262 (2019-01-11)
Excess fungicides can pose a serious threat to the soil environment. Fungicides can lower the microbiological and biochemical activity of soil and lead to yield declines. Soils contaminated with fungicides have to be remediated to maintain the optimal function of
Dganit Sadeh et al.
Journal of economic entomology, 112(2), 616-624 (2018-12-12)
The sweet potato whitefly Bemisia tabaci Genn (Hemiptera: Aleyrodidae) has been recorded to differentially prefer rosemary (Rosmarinus officinalis) varieties in commercial fields in Israel. As chemical signaling is a significant component in plant-insect interaction, the present study examined the involvement
Kang Yu et al.
Frontiers in plant science, 9, 1195-1195 (2018-09-04)
Producing quantitative and reliable measures of crop disease is essential for resistance breeding, but is challenging and time consuming using traditional phenotyping methods. Hyperspectral remote sensing has shown potential for the detection of plant diseases, but its utility for phenotyping
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