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Merck
CN

46432

Metsulfuron-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C14H15N5O6S
CAS Number:
74223-64-6
Molecular Weight:
381.36
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329757180
MDL number:
MFCD00128061
Beilstein/REAXYS Number:
587472

Key Documents

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Product Name

Metsulfuron-methyl, PESTANAL®, analytical standard

InChI

1S/C14H15N5O6S/c1-8-15-12(18-14(16-8)25-3)17-13(21)19-26(22,23)10-7-5-4-6-9(10)11(20)24-2/h4-7H,1-3H3,(H2,15,16,17,18,19,21)

SMILES string

COC(=O)c1ccccc1S(=O)(=O)NC(=O)Nc2nc(C)nc(OC)n2

InChI key

RSMUVYRMZCOLBH-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Metsulfuron-methyl may be used as an analytical reference standard for the determination of the analyte in water samples and environmental samples by various chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Metsulfuron-methyl belongs to the class of post-emergent, low-application-rate sulfonylurea herbicides. It is used in cereals and other row crops for protection against broad-leaved weeds and some grasses.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL3297
BCCD9696
BCBW9108
BCBV5730

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Determination and quantitation of ten sulfonylurea herbicides in soil samples using liquid chromatography with electrospray ionization mass spectrometric detection.
Guibiao Y, et al.
Chinese Journal of Analytical Chemistry, 34(2-3), 1207-1212 (2006)
Persistence of metsulfuron-methyl in wheat crop and soil.
Sondhia S
Environmental Monitoring and Assessment, 147(1-3), 463-469 (2008)
Preconcentration and determination of nicosulfuron, thifensulfuron-methyl and metsulfuron-methyl in water samples using carbon nanotubes packed cartridge in combination with high performance liquid chromatography.
Zhou Q, et al.
Analytica Chimica Acta, 559(2), 200-206 (2006)
Routine determination of sulfonylurea, imidazolinone, and sulfonamide herbicides at nanogram-per-liter concentrations by solid-phase extraction and liquid chromatography/mass spectrometry.
Furlong ET, et al.
The Science of the Total Environment, 248(2-3), 135-146 (2000)
R Bossi et al.
Journal of chromatography. A, 957(1), 27-36 (2002-07-10)
A new LC-MS-MS method for analysis of rainwater has been developed and validated for 53 pesticides, degradation products of pesticides and selected nitrophenols. The method was used to monitor the concentration of pesticides in rainwater at one location near Roskilde
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