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45708

Supelco

Ziram

PESTANAL®, analytical standard

Synonym(s):

Zinc dimethyldithiocarbamate, Dimethyldithiocarbamic acid zinc salt, Ziram

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About This Item

Linear Formula:
(CH3)2NCSSZnSCSN(CH3)2
CAS Number:
137-30-4
Molecular Weight:
305.82
Beilstein:
3707008
EC Number:
205-288-3
MDL number:
MFCD00064797
UNSPSC Code:
41116107
PubChem Substance ID:
329756917
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

reaction suitability

reagent type: catalyst
core: zinc

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

248-257 °C (lit.)

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

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General description

Ziram is a fungicide, widely used for the protection of vegetable crops, seed foliage and fruits. It is also employed in rubber industry as an antioxidant and vulcanization accelerator.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Ziram may be used as an analytical reference standard for the quantification of the analyte in environmental samples, grains, and vegetable samples using different analytical techniques.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Target Organs

Liver,Blood, Respiratory system

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品
农药列管产品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH8153
BCBW3982
BCBS8321V
SZBD330XV
SZBD046XV

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Determination of ziram in vegetable samples by square wave voltammetry
Qui P, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 19(11), 1337-1340 (2008)
Spectrophotometric determination of ziram (dithiocarbamate fungicide) by thiocyanate and rhodamine 6G method
Mathew L, et al.
Talanta, 42(1), 41-43 (1995)
Emanuela Corsini et al.
Toxicology and applied pharmacology, 212(2), 89-98 (2005-08-23)
Mancozeb, a polymeric complex of manganese ethylenebisdithiocarbamate with zinc salt, is widely used in agriculture as fungicide. Literature data indicate that ethylenebisdithiocarbamates (EBDTCs) may have immunomodulatory effects in humans. We have recently found in agricultural workers occupationally exposed to the
Thyneice R Taylor et al.
Toxicology mechanisms and methods, 21(8), 577-584 (2011-08-24)
Human natural killer (NK) cells are central in immune defense with their ability to lyse tumor cells and virally infected cells. Tumor formation and viral infection may increase if NK cytotoxic function is disrupted. Ziram (zinc dithiocarbamate) is used as
Josiane P Lafleur et al.
Lab on a chip, 12(22), 4651-4656 (2012-07-25)
Conventional methods of environmental analysis can be significantly improved by the development of portable microscale technologies for direct in-field sensing at remote locations. This report demonstrates the vast potential of gold nanoparticle-based microfluidic sensors for the rapid, in-field, detection of
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