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45521

Supelco

Glyphosate

PESTANAL®, analytical standard

Synonym(s):

N-(Phosphonomethyl)glycine, Glyphosate

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About This Item

Linear Formula:
(HO)2P(O)CH2NHCH2CO2H
CAS Number:
1071-83-6
Molecular Weight:
169.07
Beilstein:
2045054
EC Number:
213-997-4
MDL number:
MFCD00055350
UNSPSC Code:
41116107
PubChem Substance ID:
329756808
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

230 °C (dec.) (lit.)

application(s)

agriculture
environmental

format

neat

SMILES string

OC(=O)CNCP(O)(O)=O

InChI

1S/C3H8NO5P/c5-3(6)1-4-2-10(7,8)9/h4H,1-2H2,(H,5,6)(H2,7,8,9)

InChI key

XDDAORKBJWWYJS-UHFFFAOYSA-N

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General description

Glyphosate is a nonselective, broad-spectrum, perennial herbicide, employed at post-emergence stage for weed and vegetation control.

Application

Glyphosate may be used as an analytical reference standard for the quantification of the analyte in environmental samples using different chromatography techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

H312,H318,H411

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 2 - Eye Dam. 1

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ2151
BCCC7102
BCBZ6585
BCBW9283
BCBV0664

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Determination of glyphosate by ion chromatography
Zhu Y, et al.
Talanta, 850(1-2), 297-301 (1999)
Re-evaluation of glyphosate determination in water by liquid chromatography coupled to electrospray tandem mass spectrometry
Ibanez M, et al.
Journal of Chromatography A, 1134(1-2), 51-55 (2006)
Glyphosate: A Unique Global Herbicide (1997)
Stephen O Duke
Journal of agricultural and food chemistry, 59(11), 5835-5841 (2010-10-06)
High levels of aminomethylphosphonic acid (AMPA), the main glyphosate metabolite, have been found in glyphosate-treated, glyphosate-resistant (GR) soybean, apparently due to plant glyphosate oxidoreductase (GOX)-like activity. AMPA is mildly phytotoxic, and under some conditions the AMPA accumulating in GR soybean
Remy Babich et al.
Environment international, 144, 106019-106019 (2020-08-21)
Chronic kidney disease of unknown etiology (CKDu) is an emerging global concern affecting several agricultural communities in the Americas and South Asia. Environmental contaminants such as heavy metals (e.g., Cd, As, Pb, and V) and organic pesticides (e.g., glyphosate) in
View All Related Papers

Articles

LC/MS/MS Method for Determination of Glyphosate, AMPA, and Glufosinate in Cereals

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Simplified LC-MS/MS for Herbicides in Cereals

Glyphosate analysis: LC-MS/MS method with Supel™ Carbon LC U/HPLC column for stability and retention.

Protocols

EPA Method 547: HPLC Analysis of Glyphosate and Glyphosate Degradation Product (Aminomethyl)phosphonic Acid (AMPA)

EPA Method 547 outlines the analysis of glyphosate in drinking water by direct aqueous injection HPLC, post column derivatization, and fluorescence detection

LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

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