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Merck
CN

40870

1,2-Dimethyl-3-nitrobenzene

Selectophore, ≥99.0%

Synonym(s):

3-Nitro-o-xylene

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About This Item

Linear Formula:
(CH3)2C6H3NO2
CAS Number:
Molecular Weight:
151.16
UNSPSC Code:
26111700
NACRES:
NB.61
PubChem Substance ID:
EC Number:
201-474-3
Beilstein/REAXYS Number:
2045105
MDL number:
Assay:
≥99.0% (GC), ≥99.0%
Form:
liquid
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InChI key

FVHAWXWFPBPFOS-UHFFFAOYSA-N

InChI

1S/C8H9NO2/c1-6-4-3-5-8(7(6)2)9(10)11/h3-5H,1-2H3

SMILES string

Cc1cccc(c1C)[N+]([O-])=O

description

for ion-selective electrodes

product line

Selectophore

assay

≥99.0% (GC), ≥99.0%

Quality Level

form

liquid

refractive index

n20/D 1.543 (lit.)

bp

245 °C (lit.)

mp

7-9 °C (lit.)

density

1.129 g/mL at 25 °C (lit.)

General description

1,2,-dimethyl-3-nitrobenzene (DNB) is a plasticizer.
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Application

It was used as plasticizer in preparing K+ sensor cocktail which was used as K+ selective microelectrodes, to study nitrate interference with the sensor. It was used as internal standard for GC-MS analysis of 2,4-dichlorophenol, 2,4,6-trichlorophenol, and pentachlorophenol.

Other Notes

Additive for preparing K+-selective electrodes

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment

hcodes

Hazard Classifications

Aquatic Chronic 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

224.6 °F - closed cup

flash_point_c

107 °C - closed cup

ppe

Eyeshields, Gloves

Regulatory Information

危险化学品
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Nitrate interference with potassium-selective microelectrodes.
Cuin, Tracey Ann, et al.
Journal of Experimental Botany, 50, 1709-1712 (1999)
Brian Roland Larsen et al.
Glia, 62(4), 608-622 (2014-02-01)
Network activity in the brain is associated with a transient increase in extracellular K(+) concentration. The excess K(+) is removed from the extracellular space by mechanisms proposed to involve Kir4.1-mediated spatial buffering, the Na(+)/K(+)/2Cl(-) cotransporter 1 (NKCC1), and/or Na(+)/K(+)-ATPase activity.
Oehme, M. and Simon, W.
Analytica Chimica Acta, 86, 21-21 (1976)
Jijun Gao et al.
Chemosphere, 71(6), 1181-1187 (2007-11-27)
The chlorophenol pollutants (CPs) have been reported to occur at relatively high concentrations in some Chinese waters. To map the distribution of CPs in the surface water throughout China, samples were collected from over 600 sites in the seven major
P Wuhrmann et al.
Proceedings of the National Academy of Sciences of the United States of America, 76(2), 806-808 (1979-02-01)
Changes in nuclear K+ electrochemical activity and total nuclear K+ content in salivary glands of Chironomus tentans were measured with ion-selective microelectrodes based on valinomycin and with flameless atomic absorption spectrometry, respectively. The K+ activity increased by a factor of

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