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Merck
CN

37896

Carbofuran-3-hydroxy

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C12H15NO4
CAS Number:
16655-82-6
Molecular Weight:
237.25
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329755712
MDL number:
MFCD00143168
Beilstein/REAXYS Number:
1383873

Key Documents

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Product Name

Carbofuran-3-hydroxy, PESTANAL®, analytical standard

InChI

1S/C12H15NO4/c1-12(2)10(14)7-5-4-6-8(9(7)17-12)16-11(15)13-3/h4-6,10,14H,1-3H3,(H,13,15)

SMILES string

CNC(=O)Oc1cccc2C(O)C(C)(C)Oc12

InChI key

RHSUJRQZTQNSLL-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

impurities

≤2% water (Karl Fischer)

mp

140-148 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

storage temp.

−20°C

Quality Level

100

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Application

Carbofuran-3-hydroxy may be used as a reference standard for the determination of carbofuran-3-hydroxyn in rape plants by reverse phase high pressure liquid chromatography.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Carbofuran-3-hydroxy is one of the metabolites of the insecticide, carbofuran.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbones
GHS06

signalword

Danger

hcodes

H300

Hazard Classifications

Acute Tox. 2 Oral

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCL9283
BCCC4582
BCCB4836
BCBR5973V

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Carbofuran metabolism and toxicity in the rat.
Ferguson PW, et al.
Toxicological Sciences, 4(1), 14-21 (1984)
J Huang et al.
La Medicina del lavoro, 89 Suppl 2, S105-S111 (1999-04-28)
This paper investigates the acute effects of carbofuran in workers of two pesticide-formulating plants. Mean airborne carbofuran concentrations ranged from 0.025 to 1.115 mg/m3 in plant A and from 0.018 to 0.067 mg/m3 in plant B, respectively. In workers of
S Dulaurent et al.
Forensic science international, 176(1), 72-75 (2007-11-07)
We reported two non-fatal cases of intoxication with pesticides namely alachlor and carbofuran. Hair stand samples were collected from two men approximately 1 year after alachlor intoxication for case 1, and 14 days after the last exposure for case 2.
Direct analysis of carbofuran and 3-hydroxycarbofuran in rape plants by reverse-phase high-pressure liquid chromatography.
Y W Lee et al.
Journal of agricultural and food chemistry, 28(4), 719-722 (1980-07-01)
P W Ferguson et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 4(1), 14-21 (1984-02-01)
The influence of carbofuran metabolism on acetylcholinesterase inhibition has been defined after low dose (50 micrograms/kg, iv and oral) [carbonyl-14C]carbofuran exposures to male Sprague-Dawley rats. Red blood cell acetylcholinesterase (RBC AchE) inhibition (83% at 2 min, 37% at 15 min
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