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Merck
CN

36155

Metazachlor

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C14H16ClN3O
CAS Number:
67129-08-2
Molecular Weight:
277.75
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329755300
EC Number:
266-583-0
Beilstein/REAXYS Number:
621550
MDL number:
MFCD00055509

Key Documents

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Product Name

Metazachlor, PESTANAL®, analytical standard

InChI key

STEPQTYSZVCJPV-UHFFFAOYSA-N

InChI

1S/C14H16ClN3O/c1-11-5-3-6-12(2)14(11)18(13(19)9-15)10-17-8-4-7-16-17/h3-8H,9-10H2,1-2H3

SMILES string

Cc1cccc(C)c1N(Cn2cccn2)C(=O)CCl

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

mp

74-78 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Related Categories

Application

Metazachlor may be used as an analytical standard for the determination of metazachlor in:
  • Natural water samples by high performance liquid chromatography-electrospray-tandem mass spectrometry (HPLC-ESI-MS/MS).
  • Plant foodstuffs by capillary gas chromatography equipped with electron capture detector (ECD) as well as nitrogen phosphorus detector (NPD) followed by MS analysis in electron impact ionization (EI) mode.
  • Drinking and related waters by solid phase extraction (SPE) followed by GC-EI-MS.
  • Wastewater samples by SPE and subsequent analysis with ultra-performance liquid chromatography combined with time of flight mass spectrometry (UPLC-TOF-MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Metazachlor is an α-chloracetamide derivative which is widely used as a herbicide for weed control in the cultivation of crucifers such as rape.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCL7239
BCCH6695
BCBW2741
BCBT3309

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Kamila Lewicka et al.
Materials (Basel, Switzerland), 13(4) (2020-02-16)
The presented work aimed to test influence of poly(L-lactide-co-glycolide)-block-poly (ethylene oxide) copolymer modification by blending with grafted dextrin or maltodextrin on the course of degradation in soil and the usefulness of such material as a matrix in the controlled release
Monitoring of pesticides in drinking and related waters in NE Spain with a multiresidue SPE-GC-MS method including an estimation of the uncertainty of the analytical results
Quintana J, et al.
Journal of Chromatography A, 938(1-2), 3-13 (2001)
Ewa Szpyrka et al.
Scientific reports, 10(1), 3747-3747 (2020-03-01)
The study concerned dissipation of metazachlor and clomazone, herbicides widely used in rapeseed (Brassica napus L. subsp. napus) protection, applied to the clay soil under field and laboratory conditions. Furthermore, the uptake of these pesticide from soil by rapeseed plants
Hanne Vercampt et al.
Environmental toxicology and chemistry, 36(1), 59-70 (2016-06-28)
In accordance with realistic application approaches, a short-term 1-factorial experiment was set up to investigate the phytotoxic impact of pre-emergent application of the chloroacetamide herbicide metazachlor on Brassica napus. In addition to morphological parameters, the underlying processes that ultimately determine
Response of plankton communities in freshwater pond and stream mesocosms to the herbicide metazachlor
Mohr S, et al.
Environmental Pollution (Barking, Essex : 1987), 152(3), 530-542 (2008)
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