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Merck
CN

34534

Imidacloprid-olefin

PESTANAL®, analytical standard

Synonym(s):

1-[(6-Chloro-3-pyridinyl)methyl]-N-nitro-1H-imidazol-2-amine

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About This Item

Empirical Formula (Hill Notation):
C9H8ClN5O2
CAS Number:
Molecular Weight:
253.65
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
77101502
MDL number:
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Product Name

Imidacloprid-olefin, PESTANAL®, analytical standard

InChI

1S/C9H8ClN5O2/c10-8-2-1-7(5-12-8)6-14-4-3-11-9(14)13-15(16)17/h1-5H,6H2,(H,11,13)

SMILES string

ClC1=NC=C(CN2C(N[N+]([O-])=O)=NC=C2)C=C1

InChI key

TYLCDJYHUVCRBH-UHFFFAOYSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

Quality Level

General description

Imidacloprid-olefin is a metabolite of the insecticide, imidacloprid.

Find more information here: Neonicotinoids

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Persistence and metabolism of imidacloprid in different soils of West Bengal.
Sarkar AM, et al.
Pest Management Science, 57(7), 598-602 (2001)
Natural Beekeeping: Organic Approaches to Modern Apiculture, 2nd Edition (2013)
Maura J Hall et al.
Molecules (Basel, Switzerland), 25(12) (2020-06-18)
Consistent with the large-scale use of pesticide seed treatments in U.S. field crop production, there has been an increased use of neonicotinoid-treated corn and soybean seed over the past decade. Neonicotinoids can move downwind to adjacent off-field pollinator habitats in
Margaret L Eng et al.
The Science of the total environment, 760, 143409-143409 (2020-11-22)
Neonicotinoids are the most widely used insecticides globally, but their rapid metabolism in vertebrates makes diagnosing wildlife exposure challenging. More detailed information on the pattern of imidacloprid metabolites over time could be used to better approximate the timing and level

Protocols

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.

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