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Merck
CN

33613

Dichlormid

PESTANAL®, analytical standard

Synonym(s):

N,N-Diallyldichloroacetamide, Dichloromid

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About This Item

Empirical Formula (Hill Notation):
C8H11Cl2NO
CAS Number:
37764-25-3
Molecular Weight:
208.09
EC Number:
253-658-8
MDL number:
MFCD00072464
UNSPSC Code:
41116107
PubChem Substance ID:
329754598
NACRES:
NA.24

Key Documents

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grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

ClC(Cl)C(=O)N(CC=C)CC=C

InChI

1S/C8H11Cl2NO/c1-3-5-11(6-4-2)8(12)7(9)10/h3-4,7H,1-2,5-6H2

InChI key

YRMLFORXOOIJDR-UHFFFAOYSA-N

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General description

Dichlormid belongs to the class of dichloroacetamide safeners used to provide good protection on maize, wheat and rice grain against injury caused by pre-emergence applications of butachlor, metolachlor, chloroacetanilide and thiocarbamate.

Application

Dichlormid may be used as an analytical reference standard for the determination of the contaminant, dichlormid in animal muscle samples using gel permeation chromatography cleanup (GPC) followed by gas chromatography/mass spectrometry (GS/MS), and column chromatography tandem MS (LC/MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302 + H332

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN8085
BCCG0219
BCBT3485
SZBG069XV

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Effects of the herbicide sethoxydim and the safener dichlormid on lipid synthesis and acetyl-CoA carboxylase activity of grain sorghum.
Hatzios KK.
Zeitschrift fur Naturforschung C, 46(9-10), 934-938 (1991)
D C Holt et al.
Planta, 196(2), 295-302 (1995-01-01)
The safener-induced maize (Zea mays L.) glutathione S-transferase, GST II (EC 2.5.1.18) and another predominant isoform, GST I, were purified from extracts of maize roots treated with the safeners R-25788 (N,N-diallyl-2-dichloroacetamide) or R-29148 (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidone). The isoforms GST I and GST
The Pesticide Encyclopedia (2014)
Adam Baldwin et al.
Journal of experimental botany, 54(385), 1289-1294 (2003-03-26)
The thiocarbamates, such as pebulate (S-propyl butyl (ethyl) thiocarbamate) are a well-established class of herbicides. They inhibit fatty acid elongation, which is necessary for the biosynthesis of constituents of surface waxes and suberin and this has been proposed to be
I Jepson et al.
Plant molecular biology, 26(6), 1855-1866 (1994-12-01)
Several GSTs have been characterised in maize. GST I is a homodimer of 29 kDa subunits, GST II a hetrodimer of 27 kDa and 29 kDa subunits and GST IV a homodimer of 27 kDa subunits. We report the isolation
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