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33589

Supelco

Clothianidin

PESTANAL®, analytical standard

Synonym(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-methyl-2-nitroguanidine

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About This Item

Empirical Formula (Hill Notation):
C6H8ClN5O2S
CAS Number:
210880-92-5
Molecular Weight:
249.68
MDL number:
MFCD06200753
UNSPSC Code:
41116107
PubChem Substance ID:
329754593
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CN\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)

InChI key

PGOOBECODWQEAB-UHFFFAOYSA-N

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General description

Clothianidin is a neonicotinoid insecticide with excellent systemic action for a wide variety of insect pests, that acts effectively on nicotinic acetylcholine receptors (nAChR).
Find more information here: Neonicotinoids

Application

Clothianidin may be used as a reference standard for the analysis of the analyte in agricultural samples using dual-labeled time-resolved fluoro-immunoassay (TRFIA), followed by gas chromatography (GC).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

related product

Product No.
Description
Pricing

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ9079
BCCC1790
BCBS3968V
SZBD053XV
SZBB094XV

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Thiamethoxam is a neonicotinoid precursor converted to clothianidin in insects and plants.
Nauen R, et al.
Pesticide Biochemistry and Physiology, 76(2), 55-69 (2003)
Gennaro Di Prisco et al.
Scientific reports, 7(1), 13446-13446 (2017-10-19)
Clothianidin is a widely used neonicotinoid insecticide, which is a potent agonist of the nicotinic acetylcholine receptor in insects. This neurotoxic compound has a negative impact on insect immunity, as it down-regulates the activation of the transcription factor NF-κB. Given
Christof W Schneider et al.
PloS one, 7(1), e30023-e30023 (2012-01-19)
The development of insecticides requires valid risk assessment procedures to avoid causing harm to beneficial insects and especially to pollinators such as the honeybee Apis mellifera. In addition to testing according to current guidelines designed to detect bee mortality, tests
Chemistry of clothianidin and related compounds.
Uneme H.
Journal of Agricultural and Food Chemistry, 59(7), 2932-2937 (2010)
H Hesketh et al.
Scientific reports, 6, 37655-37655 (2016-12-21)
Concern over reported honeybee (Apis mellifera spp.) losses has highlighted chemical exposure as a risk. Current laboratory oral toxicity tests in A. mellifera spp. use short-term, maximum 96 hour, exposures which may not necessarily account for chronic and cumulative toxicity. Here
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