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33400

Supelco

Bromophos-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C8H8BrCl2O3PS
CAS Number:
Molecular Weight:
366.00
Beilstein:
1988276
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
NMR: suitable
gas chromatography (GC): suitable

mp

53-56 °C

suitability

passes test for identity (NMR)

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

COP(=S)(OC)Oc1cc(Cl)c(Br)cc1Cl

InChI

1S/C8H8BrCl2O3PS/c1-12-15(16,13-2)14-8-4-6(10)5(9)3-7(8)11/h3-4H,1-2H3

InChI key

NYQDCVLCJXRDSK-UHFFFAOYSA-N

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General description

Bromophos-methyl is an organophosphorus insecticide widely used to control a wide variety of insects in agriculture and forestry sector.

Application

Bromophos-methyl may be used as a reference standard for the determination of bromophos-methyl in biological samples using headspace solid-phase microextraction and gas chromatography with mass spectrometric detection.
Bromophos-methyl may be used as a reference standard for the determination of the insecticidel in berries using head-space solid phase microextraction with gas chromatography coupled to mass spectrometry (SPME-GC-MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

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Certificates of Analysis (COA)

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Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries.
Lambropoulou AD and Albanis AT
Journal of Chromatography A, 993(1-2), 197-203 (2003)
[Determination of bromofos, diazinon and methylpyrimifos in fruit and vegetables].
J Zadrozińska
Roczniki Panstwowego Zakladu Higieny, 28(1), 69-78 (1977-01-01)
[The effect of noxious chemicals on the sperm quality of boars used for insemination. 1. The fly control agent "omexan"].
O Schulz et al.
Archiv fur experimentelle Veterinarmedizin, 42(3), 435-443 (1988-05-01)
R D Verschoyle et al.
Toxicology and applied pharmacology, 122(2), 208-213 (1993-10-01)
In rats, 1-nitronaphthalene (1-NN) causes both pulmonary and hepatic toxicity. Pulmonary toxicity is evident as bronchiolar damage, with necrosis of Clara cells and ciliated cells, whereas hepatic injury involves vacuolation of centrilobular hepatocytes. Pretreatment with O,O,S-trimethylphosphorodithioate [OOS-MeP(S)] or p-xylene gave
P Santhoshkumar et al.
Neurotoxicology and teratology, 16(3), 227-232 (1994-05-01)
Bromophos, an organophosphorus compound, is known to cross the placental barrier. The response of the foetal brain acetylcholinesterase (AChE) to in vivo Bromophos exposure is not known. This study measured the in vivo time-course of cholinesterase (ChE) inhibition and recovery

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