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Merck
CN

32951

TDCPP

PESTANAL®, analytical standard

Synonym(s):

Tris(1,3-dichloro-2-propyl) phosphate, 1,3-Dichloro-2-propanol phosphate, Phosphoric acid tris(1,3-dichloro-2-propyl ester)

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About This Item

Empirical Formula (Hill Notation):
C9H15Cl6O4P
CAS Number:
13674-87-8
Molecular Weight:
430.90
NACRES:
NA.24
PubChem Substance ID:
329754406
UNSPSC Code:
41116107
EC Number:
237-159-2
MDL number:
MFCD00083121

Key Documents

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Product Name

TDCPP, PESTANAL®, analytical standard

InChI key

ASLWPAWFJZFCKF-UHFFFAOYSA-N

InChI

1S/C9H15Cl6O4P/c10-1-7(2-11)17-20(16,18-8(3-12)4-13)19-9(5-14)6-15/h7-9H,1-6H2

SMILES string

ClCC(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

density

1.514 g/mL at 20 °C (lit.)

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
TDCPP may be used as an analytical reference standard for the determination of the analyte in:
  • Eggs by liquid chromatography-tandem quadrupole mass spectrometry (LC-MS/MS).
  • Fish samples by gas chromatography-nitrogen-phosphorus detector (GC-NPD), LC-MS/MS and on-line turbulent flow chromatography (TFC) in conjunction with LC-MS/MS.
  • Environmental samples by GC-MS/MS.
  • Fruits and vegetables by GC-MS/MS and GC coupled with electron capture detection.

General description

TDCPP is classified under the chlorinated trialkyl organophosphate flame retardant (OPFR) group of compounds primarily utilized as additives in commercial products such as plastics, paints, textiles, furniture, etc.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Warning

hcodes

H351,H410

Hazard Classifications

Aquatic Chronic 1 - Carc. 2

Storage Class

10 - Combustible liquids

wgk

WGK 2

flash_point_f

482.0 - 485.6 °F - open cup

flash_point_c

250 - 252 °C - open cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK0213
BCBZ5176

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Multivariate optimization of the QuEChERS-GC-ECD method and pesticide investigation residues in apples, strawberries, and tomatoes produced in Brazilian south.
Lorenz JG, et al.
Journal of the Brazilian Chemical Society, 25(9), 1583-1591 (2014)
Guangyu Li et al.
Chemosphere, 186, 209-217 (2017-08-07)
Core endpoints in zebrafish embryos are crucial indicators in screening harmful effects of chemicals. In this study, we established a three-step process to more quantitatively and less-subjective determine effects of chemicals on phenotypes of developing zebrafish embryos. Embryos were exposed
Determination of organophosphorous flame retardants in fish tissues by matrix solid-phase dispersion and gas chromatography.
Campone L, et al.
Analytical and Bioanalytical Chemistry, 397(2), 799-806 (2010)
Sean P McGee et al.
Environmental health perspectives, 120(11), 1585-1591 (2012-09-29)
Chlorinated phosphate esters (CPEs) are widely used as additive flame retardants for low-density polyurethane foams and have frequently been detected at elevated concentrations within indoor environmental media. To begin characterizing the potential toxicity of CPEs on early vertebrate development, we
Analysis of organophosphorus flame retardants in environmental and biotic matrices using on-line turbulent flow chromatography-liquid chromatography-tandem mass spectrometry.
Giulivo M, et al.
Journal of Chromatography A, 1474(2), 71-78 (2016)
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