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Merck
CN

32824

Fluazifop

PESTANAL®, analytical standard

Synonym(s):

2-[4-(5-Trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid

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About This Item

Empirical Formula (Hill Notation):
C15H12F3NO4
CAS Number:
69335-91-7
Molecular Weight:
327.26
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329754341
MDL number:
MFCD00270159
Beilstein/REAXYS Number:
552236

Key Documents

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Product Name

Fluazifop, PESTANAL®, analytical standard

SMILES string

CC(Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1)C(O)=O

InChI key

YUVKUEAFAVKILW-UHFFFAOYSA-N

InChI

1S/C15H12F3NO4/c1-9(14(20)21)22-11-3-5-12(6-4-11)23-13-7-2-10(8-19-13)15(16,17)18/h2-9H,1H3,(H,20,21)

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Fluazifop may be used as an analytical reference standard for the determination of the analyte in:
  • Rainwater samples by solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS).
  • Vegetables by acetonitrile-based QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction followed by LC-MS/MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Fluazifop is one of the major metabolites of fluazifop-p-butyl, a systemic, post-emergence herbicide used for the control of annual and perennial grass weeds in non-graminaceous crops.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Warning

hcodes

H361,H400

Hazard Classifications

Aquatic Acute 1 - Repr. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCM8401
BCCM2541
BCCL7575
BCCF7942
BCCB6532

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L Várnagy et al.
Acta veterinaria Hungarica, 47(2), 271-277 (1999-05-27)
Toxicological studies on wild animals play an important role in the ecotoxicological examination of pesticides. The applied model tests enable the assessment of toxicological consequences with particular regard to the life and nutrition of wild animals in the ploughed field
E Bolygo et al.
Fresenius' journal of analytical chemistry, 368(8), 816-819 (2001-03-03)
An LC-MS-MS assay is described for fluazifop residue analysis in crops. The residues are extracted with acidified organic solvent, the esters and conjugates are hydrolysed with 6 M hydrochloric acid, then the extracts are cleaned-up by solid phase extraction using
R Bossi et al.
Journal of chromatography. A, 957(1), 27-36 (2002-07-10)
A new LC-MS-MS method for analysis of rainwater has been developed and validated for 53 pesticides, degradation products of pesticides and selected nitrophenols. The method was used to monitor the concentration of pesticides in rainwater at one location near Roskilde
Validation and uncertainty study of a comprehensive list of 160 pesticide residues in multi-class vegetables by liquid chromatography-tandem mass spectrometry.
Kmellar B, et al.
Journal of Chromatography A, 1215(1-2), 37-50 (2008)
J Hajslová et al.
Journal of chromatography, 438(1), 55-60 (1988-04-01)
Fluazifop-butyl, haloxyfop-ethoxyethyl and quizalofop-ethyl, active ingredients of new selective herbicidal preparations, as well as their metabolites converted in to corresponding methyl esters were separated on several gas chromatographic columns. Bromination of fluazifop esters increased significantly the response of the electron-capture
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