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Spirotetramat Metabolite BYI08330 enol-glucoside

PESTANAL®, analytical standard

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Synonym(s):
cis-3-(2,5-Dimethylphenyl)-8-methoxy-2-oxo-1-azaspiro [4.5]dec-3-en-4-yl β-D-glucopyranoside
Empirical Formula (Hill Notation):
C24H33NO8
CAS Number:
1172614-86-6
Molecular Weight:
463.52
UNSPSC Code:
41116107
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

−20°C

SMILES string

COC1CCC2(CC1)NC(=O)C(=C2O[C@@H]3O[C@H](CO)[C@H](O)[C@@H](O)[C@@H]3O)c4cc(C)ccc4C

InChI

1S/C24H33NO8/c1-12-4-5-13(2)15(10-12)17-21(24(25-22(17)30)8-6-14(31-3)7-9-24)33-23-20(29)19(28)18(27)16(11-26)32-23/h4-5,10,14,16,18-20,23,26-29H,6-9,11H2,1-3H3,(H,25,30)/t14?,16-,18-,19+,20-,23+,24?/m1/s1

InChI key

UZUGTDHNHPYPHX-WUMYBWKZSA-N

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General description

Spirotetramat Metabolite BYI08330 enol-glucoside is one of the major metabolites of spirotetramat in plants.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Spirotetramat Metabolite BYI08330 enol-glucoside may be used as an analytical reference standard for the determination of spirotetramat metabolite BYI08330 enol-glucoside in:
  • Fruits and vegetables by QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction based on liquid extraction/partition as well as dispersive solid phase extraction (d-SPE) and ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS) equipped with electrospray ionization (ESI) source and multiple reaction monitoring (MRM) detection.
  • Pepper samples by chemometric-assisted QuEChERS extraction and UHPLC-ESI-MS/MS.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Hazard Statements

H411

Precautionary Statements

P273

Hazard Classifications

Aquatic Chronic 2

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chemometric-assisted QuEChERS extraction method for the residual analysis of thiacloprid, spirotetramat and spirotetramat?s four metabolites in pepper: application of their dissipation patterns.
Li S, et al.
Food Chemistry, 192, 893-899 (2016)
Simultaneous determination of spirotetramat and its four metabolites in fruits and vegetables using a modified quick, easy, cheap, effective, rugged, and safe method and liquid chromatography/tandem mass spectrometry.
Zhu Y, et al.
Journal of Chromatography A, 1299, 71-77 (2013)

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