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Merck
CN

32056

Carbofuran

PESTANAL®, analytical standard

Synonym(s):

2,3-Dihydro-2,2-dimethyl-7-benzofuranol N-methylcarbamate

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About This Item

Empirical Formula (Hill Notation):
C12H15NO3
CAS Number:
Molecular Weight:
221.25
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
216-353-0
Beilstein/REAXYS Number:
1428746
MDL number:
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Product Name

Carbofuran, PESTANAL®, analytical standard

InChI key

DUEPRVBVGDRKAG-UHFFFAOYSA-N

InChI

1S/C12H15NO3/c1-12(2)7-8-5-4-6-9(10(8)16-12)15-11(14)13-3/h4-6H,7H2,1-3H3,(H,13,14)

SMILES string

CNC(=O)Oc1cccc2CC(C)(C)Oc12

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

150-153 °C (lit.)

application(s)

agriculture
environmental

format

neat

Quality Level

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Application

Carbofuran may be used as a reference standard for the determination of the analyte:
  • In well water samples by high-performance liquid chromatography employing a variable-wavelength ultraviolet detector set.
  • In fruits and vegetables by monoclonal enzyme immunoassay and high-performance liquid chromatography with fluorescence detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Carbofuran belongs to N-methylcarbamate class of chemicals used to control soil-dwelling and foliar-feeding insects on agricultural crops. Carbofuran acts by inhibiting cholinesterase enzyme activity.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 1 Oral - Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

危险化学品
剧毒化学品
农药列管产品
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Development of monoclonal antibody-based immunoassays to the N-methylcarbamate pesticide carbofuran.
Abad A, et al.
Journal of Agricultural and Food Chemistry, 47(6), 2475- 2485 (1999)
Determination of aldicarb, aldicarb sulfoxide, aldicarb sulfone and carbofuran residues in water using high-performance liquid chromatography.
Cochrane WP, et al.
Journal of Chromatography A, 243(2), 307- 314 (1982)
Determination of carbaryl, carbofuran and methiocarb in cucumbers and strawberries by monoclonal enzyme immunoassays and high-performance liquid chromatography with fluorescence detection: An analytical comparison.
Abad A, et al.
Journal of Chromatography A, 833(1), 3-12 (1999)
Kun Jia et al.
Ecotoxicology and environmental safety, 96, 61-66 (2013-07-23)
The effects of carbofuran toxicity on a genetically modified bacterial strain E. coli DPD2794 were enhanced using a new bioluminescent protocol which consisted of three consecutive steps: incubation, washing and luminescence reading. Specifically, in the first step, several concentrations of
Anna Lundqvist et al.
Ecotoxicology (London, England), 21(8), 2398-2408 (2012-09-08)
We studied the fate and bioavailability of insecticides in short-term experiments (48 h) with different hydrophobicity (3.8 pM carbofuran, 3.0 pM lindane, and 5.3 pM chlorpyrifos) across gradients in dissolved organic matter (low-, medium-, and high-DOM) in freshwater microcosms, mimicking

Protocols

-methylcarbamate 10 μg/mL; Diuron; Propham; Siduron; Methiocarb, analytical standard; Linuron 10 μg/mL; Swep 10 μg/mL; Chlorpropham 10 μg/mL; Barban; Neburon

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