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Dimethenamid

PESTANAL®, analytical standard

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Synonym(s):
2-Chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide
Empirical Formula (Hill Notation):
C12H18ClNO2S
CAS Number:
87674-68-8
Molecular Weight:
275.79
Beilstein:
8143313
MDL number:
MFCD01632376
UNSPSC Code:
41116107
PubChem Substance ID:
329753903
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COCC(C)N(C(=O)CCl)c1c(C)csc1C

InChI

1S/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3

InChI key

JLYFCTQDENRSOL-UHFFFAOYSA-N

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General description

Dimethenamid is a chloroacetamide herbicide mostly used to control broadleaf weeds and annual grasses in crops.

Application

Dimethenamid may have been used as reference standard for pesticide residue analysis from spinach, soybean and orange using supercritical fluid extraction (SFE) followed by GC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H411

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Analytical method for the determination of metolachlor, acetochlor, alachlor, dimethenamid, and their corresponding ethanesulfonic and oxanillic acid degradates in water using SPE and LC/ESI-MS/MS.
Yokley RA et.al.
Analytical Chemistry, 74(15), 3754-3759 (2002)
Gabriela K Suszter et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 52(8), 557-563 (2017-05-11)
Pesticide residues were determined in about 120 soil cores taken randomly from the top 15 cm layer of two sunflower fields about 30 days after preemergence herbicide treatments. Samples were extracted with acetone-ethyl acetate mixture and the residues were determined with GC-TSD.
Rada D Ðurović-Pejčev et al.
Journal of AOAC International (2018-10-17)
Background: The increased use of pesticides leads to permanent pollution of soil, and there is a need for continuous monitoring of these agrochemicals in soil. Objective: Three methods for the simultaneous determination of 12 pesticides belonging to eight chemical groups
Pesticide multiresidue analysis of 303 compounds using supercritical fluid extraction.
Ono Y
Analytical Sciences, 22(11), 1473-1476 (2006)
Robert A Yokley et al.
Analytical chemistry, 74(15), 3754-3759 (2002-08-15)
A Good Laboratory Practices (GLP) validated, multiresidue analytical method is presented for the determination of the chloroacetanilide herbicides metolachlor, acetochlor, and alachlor, the chloroacetamide herbicide dimethenamid, and their respective ethanesulfonic (ESA) and oxanillic (OA) acid degradates in ground and surface

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