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31510

Supelco

Bupirimate

PESTANAL®, analytical standard

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Empirical Formula (Hill Notation):
C13H24N4O3S
CAS Number:
41483-43-6
Molecular Weight:
316.42
Beilstein:
758056
EC Number:
255-391-2
MDL number:
MFCD00055518
UNSPSC Code:
41116107
PubChem Substance ID:
329753790
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCCCc1c(C)nc(NCC)nc1OS(=O)(=O)N(C)C

InChI

1S/C13H24N4O3S/c1-6-8-9-11-10(3)15-13(14-7-2)16-12(11)20-21(18,19)17(4)5/h6-9H2,1-5H3,(H,14,15,16)

InChI key

DSKJPMWIHSOYEA-UHFFFAOYSA-N

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General description

Bupirimate is an active ingredient in plant protection products and is commonly used as a systemic fungicide. It belongs to the family of pyrimidines and finds applications in controlling powdery mildew in roses and apple plantations.

Application

Bupirimate may be used as a reference standard in the determination of bupirimate in fruits using gas chromatography coupled with a flame photometric detector (GC-FPD).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Statements

H312,H317,H351,H410

Hazard Classifications

Acute Tox. 4 Dermal - Aquatic Chronic 1 - Carc. 2 - Skin Sens. 1B

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

农药列管产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Detoxification of bupirimate pesticide in aqueous solutions by electrochemical oxidation
Errami.M, et al.
Der Pharm Chem, 4, 297-310 (2012)
chromatography/quadrupole-time-of-flight mass spectrometry},
Ernst.FG, et al.
Journal of Chromatography A, 179(2), 351-354 (1979)
Yun-Hui Teng et al.
Chang Gung medical journal, 27(12), 877-886 (2005-03-10)
The purpose of this retrospective study was to determine whether epidural fentanyl-bupivacaine patient-controlled analgesia (PCA) was more efficacious and had fewer adverse effects than epidural or intravenous morphine PCA. We retrospectively retrieved data from 859 patients (mean age 64+/-7 years)
Identification of pesticide transformation products in agricultural soils using liquid chromatography/quadrupole-time-of-flight mass spectrometry.
Padilla-Sanchez.AJ, et al.
Rapid Communications in Mass Spectrometry, 26(09), 1091-1099 (2012)
M J Jongen et al.
Journal of analytical toxicology, 16(1), 60-62 (1992-01-01)
An HPLC method was developed for estimation of dermal exposure of greenhouse workers to the pesticide bupirimate. Chromatography was performed on a cyano-modified silica column with methanol-water (6:4 by volume) containing 5 g/L ammonium sulfate as eluent. UV detection at
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