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Supelco

Aldicarb-sulfoxide

PESTANAL®, analytical standard

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Empirical Formula (Hill Notation):
C7H14N2O3S
CAS Number:
1646-87-3
Molecular Weight:
206.26
Beilstein:
2212914
MDL number:
MFCD00143566
UNSPSC Code:
41116107
PubChem Substance ID:
329753707
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CNC(ON=CC(C)(C)S(C)=O)=O

InChI

1S/C7H14N2O3S/c1-7(2,13(4)11)5-9-12-6(10)8-3/h5H,1-4H3,(H,8,10)

InChI key

BXPMAGSOWXBZHS-UHFFFAOYSA-N

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General description

Aldicarb sulfoxide, cholinesterase inhibitor in insects, is formed from Temik during initial oxidation. It is persistent in soil and is rapidly translocated in plants.

Application

Aldicarb-sulfoxide may be used as a pesticide reference standard for the determination of the analyte in:
  • Fruits and vegetable using solid-phase extraction followed by liquid chromatography-atmospheric pressure chemical ionization mass spectrometry.
  • Water samples by gas chromatography/mass spectrometry (GC-MS) using short capillary columns.
  • Foodstuffs by liquid chromatography-tandem mass spectrometry (LC-MS/MS) using a triple quadrupole analyzer.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Statements

H300,H400

Precautionary Statements

P273 - P301 + P310 + P330

Hazard Classifications

Acute Tox. 1 Oral - Aquatic Acute 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Liquid chromatography/atmospheric pressure ionization--mass spectrometry in drug metabolism studies.
Kostiainen R, et al.
Journal of Mass Spectrometry : Jms, 38(4), 357-372 (2003)
Application of matrix solid phase dispersion to the determination of imidacloprid, carbaryl, aldicarb, and their main metabolites in honeybees by liquid chromatography-mass spectrometry detection.
Totti S
Talanta, 69(3), 724-729 (2006)
M Pelekis et al.
Xenobiotica; the fate of foreign compounds in biological systems, 27(11), 1113-1120 (1997-12-31)
1. The rate of sulphoxidation of aldicarb (2-methyl-2-(methylthio) propanal O-[(methylamino) carbonyl oxime], Temik) in rat hepatic, renal and pulmonary microsomes was determined by quantitating the levels of aldicarb sulphoxide and aldicarb sulphone produced during incubations. Under in vitro experimental conditions
Behavioral Responses of Heterodera rostochiensis Larvae to Aldicarb and its Sulfoxide and Sulfone.
Nelmes AJ.
Journal of Nematology, 2(3), 223-227 (1970)
High performance liquid chromatographic method for the determination of aldicarb sulfoxide in watermelon.
K C Ting et al.
Bulletin of environmental contamination and toxicology, 37(2), 192-198 (1986-08-01)
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