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306452

Sigma-Aldrich

Reactive Black 5

Dye content ≥50 %

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Synonym(s):
Remazol Black B
Empirical Formula (Hill Notation):
C26H21N5Na4O19S6
CAS Number:
Molecular Weight:
991.82
EC Number:
MDL number:
UNSPSC Code:
12171500
PubChem Substance ID:
NACRES:
NA.47

form

powder

Quality Level

composition

Dye content, ≥50%

mp

>300 °C (lit.)

density

1.21 g/cm3 at 20 °C

λmax

597 nm

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

[Na+].[Na+].[Na+].[Na+].Nc1c(N=Nc2ccc(cc2)S(=O)(=O)CCOS([O-])(=O)=O)c(cc3cc(c(N=Nc4ccc(cc4)S(=O)(=O)CCOS([O-])(=O)=O)c(O)c13)S([O-])(=O)=O)S([O-])(=O)=O

InChI

1S/C26H25N5O19S6.4Na/c27-23-22-15(13-20(53(37,38)39)24(23)30-28-16-1-5-18(6-2-16)51(33,34)11-9-49-55(43,44)45)14-21(54(40,41)42)25(26(22)32)31-29-17-3-7-19(8-4-17)52(35,36)12-10-50-56(46,47)48;;;;/h1-8,13-14,32H,9-12,27H2,(H,37,38,39)(H,40,41,42)(H,43,44,45)(H,46,47,48);;;;/q;4*+1/p-4

InChI key

HFIYIRIMGZMCPC-UHFFFAOYSA-J

Related Categories

General description

Reactive Black 5 belongs to the class of textile azo dyes. It can be biodegraded by the laccase enzyme in Ganoderma lucidum.
Reactive Black 5 is a reactive dye belonging to vinyl sulphone type. Such reactive dyes serve as colorants for many industries including paper. The functional group of the dye forms a covalent link with substrate functional group.

Application

Reactive Black 5 (RB5) has been:
  • used in an optimization study on the photocatalytic degradation of RB5 dye in synthetic greywater effluent (i.e. aqueous RB5 in distilled water), in order to understand the effects of different photoreactor parameters on the degradation kinetics.
  • as a textile dye to investigate the anaerobic reduction in upflow stirred packed-bed reactors (USPBRs) with biological activated carbon (BAC) system
  • used in the performance evaluation of dye removal forlarge molecule substance

Pictograms

Health hazard

Signal Word

Danger

Hazard Statements

Hazard Classifications

Resp. Sens. 1 - Skin Sens. 1

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Ultrasonic mineralization of a reactive textile azo dye, remazol black B
Vinodgopal K, et al.
Water Research, 32(12), 3646-3650 (1998)
Evaluation of Titanium dioxide photocatalytic technology for the treatment of reactive Black 5 dye in synthetic and real greywater effluents
Chong MN, et al.
Journal of Cleaner Production, 89, 196-202 (2015)
Yen-Hui Lin et al.
Biodegradation, 24(1), 137-152 (2012-06-28)
A non-steady-state mathematical model system for the kinetics of adsorption and biodegradation of reactive black 5 (RB5) by Funalia trogii (F. trogii) ATCC 200800 biofilm on fly ash-chitosan bead in the fluidized bed process was derived. The mechanisms in the
Ceněk Novotný et al.
Bioresource technology, 114, 241-246 (2012-04-20)
Biodegradation potential of Dichomitus squalens in biofilm cultures and rotating biological contactor (RBC) was investigated. The fungus formed thick biofilms on inert and lignocellulosic supports and exhibited stable activities of laccase and manganese peroxidase to reach 40-62 and 25-32% decolorization
Hatice Atacag Erkurt
Biodegradation of Azo Dyes (2010)

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