293733
Benzophenone imine
95%
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About This Item
Linear Formula:
(C6H5)2C=NH
CAS Number:
Molecular Weight:
181.23
UNSPSC Code:
12171500
NACRES:
NA.47
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1100371
InChI
1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
SMILES string
N=C(c1ccccc1)c2ccccc2
InChI key
SXZIXHOMFPUIRK-UHFFFAOYSA-N
assay
95%
form
liquid
technique(s)
titration: suitable
Quality Level
bp
151-153 °C/10 mmHg (lit.)
density
1.08 g/mL at 25 °C (lit.)
application(s)
diagnostic assay manufacturing
hematology
histology
storage temp.
room temp
Related Categories
General description
Benzophenone imine plays a vital role as an ammonia surrogate. It is primarily used as ammonia equivalents for the selective formation of protected primary amines. Benzophenone imine is useful as a synthetic intermediate, especially for the synthesis of glycine Schiff base.
Application
Benzophenone imine is useful for the preparation of nitrile yield dimers.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
228.2 °F - closed cup
flash_point_c
109 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Suzanne Fergus et al.
The Journal of organic chemistry, 69(14), 4663-4669 (2004-07-03)
A series of novel hexaaryl diazatrienes 5 ("nitrile ylide dimers") were synthesized directly from the corresponding diaryl ketimines 12 and dichlorotoluenes 13 in a facile one-pot synthesis. The carbene character of the nitrile ylides was investigated by varying the substituents
Lukas Lohmeyer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(26), 5834-5845 (2020-02-06)
New redox-active 1,2,5,6-tetrakis(guanidino)-naphthalene compounds, isolable and storable in the neutral and deep-green dicationic redox states and oxidisable further in two one-electron steps to the tetracations, are reported. Protonation switches on blue fluorescence, with the fluorescence intensity (quantum yield) increasing with
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