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27467

Sigma-Aldrich

(+)-Citronellal

purum, ≥97.0% (sum of enantiomers, GC)

Synonym(s):

(3R)-3,7-Dimethyl-6-octenal

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About This Item

Empirical Formula (Hill Notation):
C10H18O
CAS Number:
2385-77-5
Molecular Weight:
154.25
Beilstein:
1720791
EC Number:
219-194-5
MDL number:
MFCD00067089
UNSPSC Code:
12352000

grade

purum

Assay

≥97.0% (sum of enantiomers, GC)

optical activity

[α]20/D +16±1°, neat

refractive index

n20/D 1.447

storage temp.

2-8°C

SMILES string

C[C@H](CC\C=C(\C)C)CC=O

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Other Notes

Monoterpene used as chiral building block; e.g. ozonolysis; reaction with Grignard reagents; Wittig and similar reactions

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L.F. Tietze et al.
Organic Syntheses, 71, 167-167 (1993)
Y.C. Chiang et al.
The Journal of Organic Chemistry, 54, 5708-5708 (1989)
J. Leder et al.
Tetrahedron Letters, 24, 1463-1463 (1983)
L.F. Tietze et al.
Angewandte Chemie (International Edition in English), 99, 1309-1309 (1987)
K. Mori et al.
Tetrahedron Letters, 22, 4433-4433 (1981)

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