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Merck
CN

259225

1,5-Diphenylcarbazide

ACS reagent grade, solid

Synonym(s):

DPC, 1,5-Diphenylcarbohydrazide, sym.-Diphenylcarbazide

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About This Item

Linear Formula:
C6H5NHNHCONHNHC6H5
CAS Number:
Molecular Weight:
242.28
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
205-403-7
MDL number:
Beilstein/REAXYS Number:
752039
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Product Name

1,5-Diphenylcarbazide, ACS reagent

InChI key

KSPIHGBHKVISFI-UHFFFAOYSA-N

InChI

1S/C13H14N4O/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14-15H,(H2,16,17,18)

SMILES string

O=C(NNc1ccccc1)NNc2ccccc2

grade

ACS reagent

form

solid

ign. residue

≤0.05%

mp

170-175 °C (lit.)
173-176 °C

solubility

aqueous acetone: passes test

density

1,31  g/cm3

suitability

passes test for sensitivity to chromate

functional group

amine
hydrazide

Quality Level

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Application

1,5-Diphenylcarbazide may be used in the following processes:
  • As a reagent for the quantification of palladium and platinum by spectrophotometry.
  • As a mediator for the functionalization of carbon paste electrodes employed in the estimation of Hg(II) ions by differential pulse voltammetry.
  • Fabrication of gold nanoparticles that can be employed for the detection of chromium (VI) ions via colorimetry.

General description

1,5-Diphenylcarbazide is a colorimetric reagent commonly employed in the determination of trace metals.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Spectrophotometric determination of platinum and palladium with 1, 5-diphenylcarbazide
Brajter K, et al.
Fresenius Journal of Analytical Chemistry, 328(1), 598-598 (1987)
Photometric and visual detection of Cr (VI) using gold nanoparticles modified with 1, 5-diphenylcarbazide.
Liu, L, et al.
Microchimica Acta, 1-7 (2016)
Oxidation of 1,5-diphenylcarbazide as a measure of photosystem 2 activity in subchloroplast fragments.
L P Vernon et al.
Biochemical and biophysical research communications, 36(6), 878-884 (1969-09-10)
Determination of hexavalent chromium by species specific isotope dilution mass spectrometry and ion chromatography-1, 5-diphenylcarbazide spectrophotometry.
Tirez K, et al.
Journal of Analytical Atomic Spectrometry, 18(8), 922-932 (2003)
Surface-enhanced Raman scattering and DFT investigation of 1, 5-diphenylcarbazide and its metal complexes with Ca (II), Mn (II), Fe (III) and Cu (II).
Szabo L, et al.
Journal of Molecular Structure, 1073, 10-17 (2014)

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