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Sigma-Aldrich

Potassium sodium tartrate tetrahydrate

puriss., 99.0-101.0% (calc. on H2O free substance), meets analytical specification of Ph. Eur., BP, USP, FC, E 337

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Synonym(s):
L(+)-Tartaric acid potassium Sodium salt, Rochelle salt, Seignette salt
Linear Formula:
KOCOCH(OH)CH(OH)COONa · 4H2O
CAS Number:
Molecular Weight:
282.22
Beilstein:
6113568
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21

grade

puriss.

Quality Level

Assay

99.0-101.0% (calc. on H2O free substance)

form

solid

optical activity

[α]20/D +28.0 to +30.0°

quality

meets analytical specification of Ph. Eur., BP, USP, FC, E 337

impurities

acidity or alkalinity, in accordance
residual solvent, complies
≤0.001% heavy metals (as Pb)
≤0.003% total nitrogen (N)
≤0.004% ammonium (NH4)
≤0.004% free alkali (as NaOH)
≤0.0075% free acid (as C4H6O6)
24-26% water (Karl Fischer)

loss

21-26% loss on drying, 150 °C, 3 h

pH

6.5-8.5 (20 °C, 1%)

anion traces

chloride (Cl-): ≤20 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

As: ≤1 mg/kg
Ba:, in accordance
Ca: ≤50 mg/kg
Cu: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
Pb: ≤2 mg/kg
Zn: ≤10 mg/kg

suitability

passes test for appearance of solution

SMILES string

O.O.O.O.[Na+].[K+].O[C@H]([C@@H](O)C([O-])=O)C([O-])=O

InChI

1S/C4H6O6.K.Na.4H2O/c5-1(3(7)8)2(6)4(9)10;;;;;;/h1-2,5-6H,(H,7,8)(H,9,10);;;4*1H2/q;2*+1;;;;/p-2/t1-,2-;;;;;;/m1....../s1

InChI key

VZOPRCCTKLAGPN-ZFJVMAEJSA-L

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General description

Potassium sodium tartrate tetrahydrate (Rochelle salt) exists in the ferroelectric phase in the temperature range of 255 to 297K. In this phase, it crystallizes in the monoclinic system and exhibits space group P21. Saturated aqueous solution of potassium sodium tartrate (Rochelle salt) has been used for the preparation of its tetrahydrate crystals.
Potassium sodium tartrate tetrahydrate is a ferroelectric crystal with a high piezoelectric effect and electromechanical coupling coefficient.

Application

Potassium sodium tartrate tetrahydrate has been used in the β-1,3-glucanase activity assay.
Potassium sodium tartrate tetrahydrate may be used as a component to prepare DNS (3,5- dinitrosalicylic acid) reagent and Fehling′s solution B, which are used in the determination of reducing sugar.

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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