Skip to Content
Merck
CN

157775

Phosphorus pentachloride

reagent grade, 95%

Synonym(s):

Phosphorus(V) chloride

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
PCl5
CAS Number:
10026-13-8
Molecular Weight:
208.24
NACRES:
NA.21
PubChem Substance ID:
24849700
UNSPSC Code:
12352300
EC Number:
233-060-3
MDL number:
MFCD00011439
Assay:
95%
Grade:
reagent grade
Form:
powder

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Phosphorus pentachloride, reagent grade, 95%

InChI key

UHZYTMXLRWXGPK-UHFFFAOYSA-N

InChI

1S/Cl5P/c1-6(2,3,4)5

SMILES string

ClP(Cl)(Cl)(Cl)Cl

grade

reagent grade

vapor pressure

<1 mmHg ( 20 °C)

assay

95%

form

powder

pH

1 (5 g/L)

mp

179-181 °C (subl.) (lit.)

Quality Level

200

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Phosphorus pentachloride may be used in the synthesis of following compounds:
  • benzenesulfonyl chloride
  • malonic dinitrile
  • aromatic sulfonyl chlorides

Phosphorus pentachloride may be used as halogenating reagent to convert any substituted aldehyde into the corresponding vinyl halide. It can also undergo reaction with ammonium chloride to yield linear phosphazenes and cyclophosphazenes.

General description

Phosphorus pentachloride is a light yellow colored phosphorous halide. It participates in the synthesis of thiazoline analogs.

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Inhalation

target_organs

Respiratory Tract

supp_hazards

EUH014,EUH029

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 1

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCX2611
SDBB2171
MKCT3345
STBL0604
STBK7618

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Ley.VS
Comprehensive Organic Functional Group Transformations II, 2 (1995)
Allcock H
Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems (2012)
Ley.VS et al.
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond (2005)
Eagleson M.
Concise Encyclopedia Chemistry, 120-120 (1994)
Synthetic studies of thiazoline and thiazolidine-containing natural products-1. Phosphorus pentachloride-mediated thiazoline construction reaction.
Ino A and Murabayashi A.
Tetrahedron, 55(34), 10271-10282 (1999)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service