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Merck
CN

14765

Thallium(I) acetate

≥97.0%, solid

Synonym(s):

TlOAc, Acetic acid thallium(I) salt

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About This Item

Linear Formula:
CH3COOTl
CAS Number:
563-68-8
Molecular Weight:
263.43
NACRES:
NA.22
PubChem Substance ID:
57647193
UNSPSC Code:
12161600
EC Number:
209-257-5
MDL number:
MFCD00013045
Beilstein/REAXYS Number:
3693914

Key Documents

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Product Name

Thallium(I) acetate, purum, ≥97.0%

InChI key

HQOJMTATBXYHNR-UHFFFAOYSA-M

InChI

1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1

SMILES string

CC(=O)O[Tl]

grade

purum

assay

≥97.0%

form

solid

reaction suitability

core: thallium
reagent type: catalyst

Quality Level

200

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Related Categories

Application

  • Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).

General description

Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.

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Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Regulatory Information

铊类化学品
危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
BCCN1093
BCCM9606
BCCL9073
BCCK0233
BCCH8281

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Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Vicki A Luna et al.
Journal of microbiological methods, 79(3), 301-306 (2009-10-08)
To prove linkage between an environmental sample and an anthrax case, there must be isolates obtained from both that can be compared. Although Bacillus anthracis is easily isolated from powder samples, isolating it from soil is difficult because of the
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