All Photos(1)
Synonym(s):
Manganese dichloride monohydrate
Linear Formula:
MnCl2 · H2O
CAS Number:
Molecular Weight:
143.86
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
Assay
≥97.0%
form
powder
reaction suitability
core: manganese
reagent type: catalyst
impurities
≤0.01% heavy metals (as Pb)
anion traces
sulfate (SO42-): ≤1000 mg/kg
cation traces
Fe: ≤200 mg/kg
SMILES string
O.Cl[Mn]Cl
InChI
1S/2ClH.Mn.H2O/h2*1H;;1H2/q;;+2;/p-2
InChI key
BXRRQHBNBXJZBQ-UHFFFAOYSA-L
Related Categories
Application
Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2
Target Organs
Brain
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Cahiez, G.; Alami, M.
Tetrahedron Letters, 30, 3541-3541 (1989)
Cahiez, G.; Laboue, B.
Tetrahedron Letters, 33, 4439-4439 (1992)
Fujii, H.; Oshima, K.; Utimoto, K.
Tetrahedron Letters, 32, 6147-6147 (1991)
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