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Merck
CN

03858

Dimethylglyoxime

≥97.0% (TLC)

Synonym(s):

dmgH2, 2,3-Butanedione dioxime, Diacetyldioxime

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About This Item

Linear Formula:
CH3C(=NOH)C(=NOH)CH3
CAS Number:
Molecular Weight:
116.12
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-420-1
Beilstein/REAXYS Number:
506731
MDL number:
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Product Name

Dimethylglyoxime, ≥97.0% (TLC)

InChI key

JGUQDUKBUKFFRO-GGWOSOGESA-N

InChI

1S/C4H8N2O2/c1-3(5-7)4(2)6-8/h7-8H,1-2H3/b5-3+,6-4+

SMILES string

CC(=N/O)\C(C)=N\O

assay

≥97.0% (TLC)

form

powder

mp

240-241 °C (lit.)

functional group

amine
oxime

Quality Level

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Application

Dimethylglyoxime can be used:
  • As a ligand for the synthesis of cobaloxime complexes which are used as electrocatalysts for the production of hydrogen by electroreduction of protons.
  • As a precipitant for the synthesis of NiO and CuI nanoparticles.P

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Synthesis and characteristics of NiO nanoparticles by thermal decomposition of nickel dimethylglyoximate rods.
Li X, et al.
Solid State Communications, 137(11), 581-584 (2006)
Proton electroreduction catalyzed by cobaloximes: Functional models for hydrogenases.
Razavet M, et al.
Inorganic Chemistry, 44(13), 4786-4795 (2005)
Hua-Jian Xu et al.
Organic & biomolecular chemistry, 10(13), 2562-2568 (2012-02-23)
CuI nanoparticles efficiently catalyzed the C-S cross coupling of aryl and alkyl thiols with aryl halides in the absence of ligands on water under mild conditions. A wide range of diaryl sulfides and aryl alkyl sulfides are synthesized in good
Jacob Pontoppidan Thyssen et al.
Contact dermatitis, 59(1), 38-42 (2008-06-10)
Nickel dermatitis may be caused by frequent and prolonged use of cell phones. Because little is known about the frequency of nickel release from cell phones, it is difficult to estimate the risk of nickel sensitization and dermatitis among their
Jacob P Thyssen et al.
Contact dermatitis, 62(5), 279-288 (2010-06-12)
The accuracy of the dimethylglyoxime (DMG) nickel spot test has been questioned because of false negative and positive test reactions. The EN 1811, a European standard reference method developed by the European Committee for Standardization (CEN), is fine-tuned to estimate

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