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Key Documents

Safety Information

00213

Sigma-Aldrich

Benzoyl peroxide blend with dicyclohexyl phthalate

technical, ~50% (T)

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About This Item

Empirical Formula (Hill Notation):
C14H10O4
Molecular Weight:
242.23
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:

grade

technical

form

solid

reaction suitability

reagent type: oxidant

concentration

~50% (T)

impurities

≤0.5% water

storage temp.

2-8°C

SMILES string

O=C(OOC(=O)c1ccccc1)c2ccccc2

InChI

1S/C14H10O4/c15-13(11-7-3-1-4-8-11)17-18-14(16)12-9-5-2-6-10-12/h1-10H

InChI key

OMPJBNCRMGITSC-UHFFFAOYSA-N

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Application

  • Oxidizing agent
  • Crosslinking agent
  • Oxidizer in palladium-catalyzed oxidative allylic C-H silylation

Packaging

in inert filler with plasticizer (dicyclohexyl phthalate)

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Org. Perox. D - Repr. 1B - Skin Sens. 1

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Roy, P. K.; et al.
Journal of Applied Polymer Science. Applied Polymer Symposium, 122, 2765-2765 (2011)
Johanna M Larsson et al.
Organic letters, 13(7), 1888-1891 (2011-03-10)
Palladium-catalyzed allylic C-H silylation was performed with use of hexamethyldisilane as the silyl source. These C-H functionalization reactions occur only in the presence of hypervalent iodine reagents or other strong oxidants and proceed with excellent regioselectivity, providing the linear allylic
Opeida, I. A.; et al.
Petroleum Chemistry (Neftekhimiya), 51, 226-226 (2011)
Su, J.; et al.
Polym. Chem., 2, 2021-2021 (2011)
Meital Bloch et al.
International journal of pharmaceutics, 478(2), 504-516 (2014-12-02)
To increase colonoscopy capability to discriminate benign from malignant polyps, we suggest combining two imaging approaches based on targeted polymeric platforms. Water-soluble cationized polyacrylamide (CPAA) was tagged with the near infrared (NIR) dye IR-783-S-Ph-COOH to form Flu-CPAA. The recognition peptide

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