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Merck
CN

30-2480

Tin(II) chloride dihydrate

JIS special grade, ≥97.0%

Synonym(s):

Stannous chloride dihydrate

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About This Item

Linear Formula:
SnCl2 · 2H2O
CAS Number:
Molecular Weight:
225.65
UNSPSC Code:
12352302
PubChem Substance ID:
MDL number:
Assay:
≥97.0%
Grade:
JIS special grade
Form:
solid
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InChI

1S/2ClH.2H2O.Sn/h2*1H;2*1H2;/q;;;;+2/p-2

SMILES string

O.O.Cl[SnH2]Cl

InChI key

FWPIDFUJEMBDLS-UHFFFAOYSA-L

grade

JIS special grade

assay

≥97.0%

form

solid

reaction suitability

reagent type: catalyst
core: tin

availability

available only in Japan

mp

37-38 °C (dec.) (lit.)

storage temp.

2-8°C

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Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

target_organs

Cardio-vascular system, Respiratory system

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Sher Bahadar Khan
Carbohydrate polymers, 242, 116286-116286 (2020-06-23)
Efficient nano-catalysts based-on metal nanoparticles (copper, silver and iron) supported on carbohydrate polymer (cotton cellulose) nanocomposite with long-term stability and efficient hydrogen production and removal of organic pollutants has been developed. The catalytic efficiency of the developed materials was evaluated
David J Hallett et al.
Organic & biomolecular chemistry, 10(30), 6130-6158 (2012-04-20)
Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoates 49. This stereoselectivity, controlled by the chirality of the stannane, dominates over any intrinsic stereochemical
Grégory Dupeyre et al.
Organic & biomolecular chemistry, 9(22), 7780-7790 (2011-10-07)
A six-step one-pot reaction was designed for synthesizing homodimeric 7-phenylindolo[3,2-a]carbazoles from 1H-indoles and β-nitrostyrenes, in the presence of SnCl(2)·2H(2)O. The reactions proceeded under very mild conditions and the desired heterocycles were obtained in moderate to good yields. An unprecedented mechanism
Amit Pratap Singh et al.
Journal of the American Chemical Society, 134(10), 4998-5003 (2012-02-15)
Cationic and anionic species of heavier low-valent group 14 elements are intriguing targets in main group chemistry due to their synthetic potential and industrial applications. In the present study, we describe the synthesis of cationic (MCl(+)) and anionic (MCl(3)(-)) species
Fa-tang Li et al.
Journal of hazardous materials, 205-206, 164-170 (2012-01-11)
A new C5H9NO·SnCl2 coordinated ionic liquid (IL) was prepared by reacting N-methyl-pyrrolidone with anhydrous SnCl2. Desulfurization of dibenzothiophene (DBT) via extraction and oxidation with C5H9NO·SnCl2 IL as extractant, H2O2 and equal mol of CH3COOH as oxidants was investigated. The Nernst

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