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28-5700

Sigma-Aldrich

Sulfamic acid

JIS special grade, ≥99.5%

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Synonym(s):
Amidosulfonic acid
Linear Formula:
NH2SO3H
CAS Number:
5329-14-6
Molecular Weight:
97.09
EC Number:
226-218-8
MDL number:
MFCD00011603
UNSPSC Code:
12352106
PubChem Substance ID:
329753241

grade

JIS special grade

Assay

≥99.5%

form

solid

availability

available only in Japan

mp

215-225 °C (dec.) (lit.)

solubility

water: 213 g/L at 20 °C
water: 470 g/L at 80 °C

density

2.151 g/cm3 at 25 °C

SMILES string

NS(O)(=O)=O

InChI

1S/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

IIACRCGMVDHOTQ-UHFFFAOYSA-N

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H412

Precautionary Statements

P273 - P305 + P351 + P338

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Toolika Agrawal et al.
Organic letters, 15(1), 96-99 (2012-12-19)
The iron-catalyzed cross-coupling of aryl sulfamates and tosylates has been achieved with primary and secondary alkyl Grignards. This study of iron-catalyzed cross-coupling reactions also examines the isomerization and β-hydride elimination problems that are associated with the use of isopropyl nucleophiles.
Daniel Can et al.
Angewandte Chemie (International ed. in English), 51(14), 3354-3357 (2012-02-22)
Enhanced receptor selectivity: carbonic anhydrase inhibitors are relevant for both cancer diagnosis and therapy. Combining non-radioactive Re compounds with their radioactive (99m)Tc homologs enables the use of identical molecules for therapy and imaging (theragnostic). The syntheses and in vitro evaluation
Derek J Langeslay et al.
Analytical chemistry, 83(20), 8006-8010 (2011-09-15)
Sulfamate (NHSO(3)(-)) groups are critically important structural elements of the glycosaminoglycans heparin and heparan sulfate (HS). Experimental conditions are presented for detection of the sulfamate (1)H NMR resonances in aqueous solution. NMR spectra reported for N-sulfoglucosamine (GlcNS) and the synthetic
Jean-Yves Winum et al.
Bioorganic & medicinal chemistry, 21(6), 1419-1426 (2012-12-04)
Targeting tumour associated carbonic anhydrase (CA, EC 4.2.1.1) isoforms IX and XII is now considered as a pertinent approach for the development of new cancer therapeutics against hypoxic tumours. In the last period, with the help of X-ray crystallography, much
Cobalt-catalyzed direct arylation and benzylation by C-H/C-O cleavage with sulfamates, carbamates, and phosphates.
Weifeng Song et al.
Angewandte Chemie (International ed. in English), 51(33), 8251-8254 (2012-07-14)
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