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05-4600

Sigma-Aldrich

Chromium(VI) oxide

SAJ special grade, ≥98.0%

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Synonym(s):
Chromic anhydride
Empirical Formula (Hill Notation):
CrO3
CAS Number:
Molecular Weight:
99.99
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:

grade

SAJ special grade

Assay

≥98.0%

form

solid

availability

available only in Japan

pH

<1 (20 °C, 100 g/L)

mp

196 °C (dec.) (lit.)

SMILES string

O=[Cr](=O)=O

InChI

1S/Cr.3O

InChI key

WGLPBDUCMAPZCE-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 1B - Ox. Sol. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Respiratory system

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Francis Pierre et al.
International archives of occupational and environmental health, 81(3), 321-329 (2007-07-03)
This study is concerned with two specific chromium (Cr) exposure situations at a hard-process electroplating company. Its aims are to define variations in urinary Cr concentration and to clarify their exposure relationships. Airborne chromium exposure and urinary excretion were measured
S Y Shiau et al.
The Journal of nutrition, 123(10), 1747-1753 (1993-10-01)
An experiment was conducted to study the influence of three different forms of chromium (CrCl3.6H2O, Na2CrO4.4H2O and Cr2O3) on the utilization of two carbohydrates (glucose and cornstarch) by juvenile hybrid tilapia (Oreochromis niloticus x O. aureus). Average initial body weight
Li-Hong Huang et al.
Molecules (Basel, Switzerland), 10(7), 794-797 (2007-11-17)
A selective oxidation of primary alcohols to the corresponding aldehydes by shaking with chromium trioxide supported on aluminium silicate at room temperature under solvent free conditions is reported. This new procedure can also oxidise secondary alcohols.
L Vayssieres et al.
Journal of nanoscience and nanotechnology, 1(4), 385-388 (2003-08-14)
We are reporting here on the inexpensive fabrication and optical properties of an iron(III) oxide-chromium(III) oxide nanocomposite thin film of corundum crystal structure. Its novel and unique-designed architecture consists of uniformed, well-defined and oriented nanorods of Hematite (alpha-Fe2O3) of 50
Adam Szelag et al.
Polish journal of pharmacology, 55(6), 1097-1103 (2004-01-20)
Hexavalent chromium compounds exhibit higher toxicity than its trivalent compounds since chromium ions in the +6 oxidation state easily cross biological membranes. It has recently been proposed that substances reducing chromium ions from the +6 to the less toxic +3

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