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Safety Information

8.52089

Sigma-Aldrich

Fmoc-Dpr(Mtt)-OH

Novabiochem®

Synonym(s):

Fmoc-Dpr(Mtt)-OH, N-α-Fmoc-N-β-4-methyltrityl-L-diaminopropionic acid

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1 G
CN¥3,501.28
5 G
CN¥14,135.33

CN¥3,501.28

Estimated to ship onJune 06, 2025Details

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1 G
CN¥3,501.28
5 G
CN¥14,135.33

About This Item

Empirical Formula (Hill Notation):
C38H34N2O4
CAS Number:
654670-89-0
Molecular Weight:
582.69
MDL number:
MFCD02094097
UNSPSC Code:
12352209
NACRES:
NA.22

CN¥3,501.28

Estimated to ship onJune 06, 2025Details

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Request a Bulk Order

Quality Level

200

product line

Novabiochem®

Assay

≥95% (TLC)
≥95.0% (HPLC)

form

powder

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

manufacturer/tradename

Novabiochem®

application(s)

peptide synthesis

functional group

amine

storage temp.

15-25°C

SMILES string

N([C@@H](CNC(c6ccc(cc6)C)(c5ccccc5)c4ccccc4)C(=O)O)C(=O)OCC1c2c(cccc2)c3c1cccc3

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Fmoc-Dpr(Mtt)-OH Novabiochem®

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Fmoc-Dab(Mtt)-OH

Fmoc-Orn(Mtt)-OH Novabiochem®

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Fmoc-Orn(Mtt)-OH

Fmoc-Lys(Mtt)-OH Novabiochem®

852065

Fmoc-Lys(Mtt)-OH

form

powder

form

powder

form

powder

form

powder

functional group

amine

functional group

amine

functional group

amine

functional group

amine

assay

≥95% (TLC), ≥95.0% (HPLC)

assay

≥95% (TLC), ≥95.0% (HPLC)

assay

≥90.0% (acidimetric), ≥98% (TLC), ≥98.0% (HPLC)

assay

≥95.0% (acidimetric), ≥98% (TLC), ≥98.0% (HPLC)

product line

Novabiochem®

product line

Novabiochem®

product line

Novabiochem®

product line

Novabiochem®

storage temp.

15-25°C

storage temp.

15-25°C

storage temp.

15-25°C

storage temp.

2-8°C

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

General description

The side-chain Mtt group can be selectively removed with 1% TFA in DCM [1,2,3] or DCM/HFIP/TFE/TES (6.5:2:1:0.5) [4], making this an excellent derivative for the synthesis of branched peptides and peptides modified at the Dpr side-chain [4,5], and for the construction of templates and multifunctionalized resins for combinatorial synthesis[6].

Associated Protocols and Technical Articles
Cleavage and Deprotection Protocols for Fmoc SPPS

Literature references

[1] K. Barlos, et al., C. H. Schneider & A. N. Eberle (Eds), ESCOM, Leiden, 1993, pp. 283.
[2] A. Aletras, et al. (1995) Int. J. Peptide Protein Res., 45, 488.
[3] L. Bourel, et al. (2000) J. Peptide Sci., 6, 264.
[4] K. Barlos, personal communication.
[5] P. Hoogerhout, et al. (1999) J. Peptide Res., 54, 436.
[6] C. Park & K. Burgess (2001) J. Comb. Chem., 3, 257.

Linkage

Replaces: 04-12-1204

Analysis Note

Color (visual): white to slight yellow to beige
Appearance of substance (visual): powder
Identity (IR): passes test
Optical rotation α 25/D (c=1 in methanol): +10.0 - +13.0 °
Purity (TLC(157A)): ≥ 95 %
Assay (HPLC, area%): ≥ 95.0 % (a/a)
Solubility (1 mmole in 2 ml DMF): clearly soluble

To see the solvent systems used for TLC of Novabiochem® products please click here.

Legal Information

Novabiochem is a registered trademark of Merck KGaA, Darmstadt, Germany

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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