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A-157

Supelco

4-ANPP-D5 solution

100 μg/mL in methanol, certified reference material, ampule of 0.5 mL, Cerilliant®

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Empirical Formula (Hill Notation):
C19H19D5N2
CAS Number:
1189466-15-6
Molecular Weight:
285.44
UNSPSC Code:
12352200
NACRES:
NA.24

grade

certified reference material

Quality Level

300

form

liquid

feature

Snap-N-Spike®/Snap-N-Shoot®

packaging

ampule of 0.5 mL

manufacturer/tradename

Cerilliant®

drug control

Decreto Lei 15/93: Tabela IA (Portugal)

concentration

100 μg/mL in methanol

technique(s)

gas chromatography (GC): suitable
liquid chromatography (LC): suitable

application(s)

forensics and toxicology

format

single component solution

storage temp.

−20°C

SMILES string

[2H]C1=C([2H])C([2H])=C([2H])C([2H])=C1NC(CC2)CCN2CCC3=CC=CC=C3

InChI

1S/C19H24N2/c1-3-7-17(8-4-1)11-14-21-15-12-19(13-16-21)20-18-9-5-2-6-10-18/h1-10,19-20H,11-16H2/i2D,5D,6D,9D,10D

InChI key

ZCMDXDQUYIWEKB-OUHXUHDZSA-N

Related Categories

General description

4-ANPP, also known as Despropionyl fentanyl, is an intermediate in the synthesis of fentanyl and related opioids and is often found as an impurity in fentanyl preparations. This stable-labeled internal standard is suitable for quantification of 4-ANPP levels in urine or other matrices by LC/MS or GC/MS for clinical toxicology, forensic analysis, prescription monitoring, or urine drug testing applications. This Certified Spiking Solution® is supplied in a convenient US DEA-exempt solution format.

Application

  • A quantitative LC-MS/MS analysis of Xylazine, p-Fluorofentanyl, Fentanyl and Fentanyl-Related compounds in postmortem blood. This study demonstrates the application of 4-ANPP in the quantitative analysis of opioid-related substances using liquid chromatography-tandem mass spectrometry (LC-MS/MS). This technique is essential for forensic toxicology, particularly in identifying and quantifying substances in postmortem blood samples, which is crucial for understanding opioid metabolism and contributing to opioid research (Truver et al., 2024).

Legal Information

CERILLIANT is a registered trademark of Merck KGaA, Darmstadt, Germany
CERTIFIED SPIKING SOLUTION is a registered trademark of Cerilliant Corporation
Snap-N-Shoot is a registered trademark of Cerilliant Corporation
Snap-N-Spike is a registered trademark of Merck KGaA, Darmstadt, Germany

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Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Target Organs

Eyes

WGK

WGK 2

Regulatory Information

监管及禁止进口产品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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