Skip to Content
Merck
CN
All Photos(1)

Documents

Safety Information

W335304

Sigma-Aldrich

cis-3-Hexenyl formate

≥95%, FG

Synonym(s):

(Z)-3-Hexen-1-yl formate

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
HCO2CH2CH2CH=CHC2H5
CAS Number:
33467-73-1
Molecular Weight:
128.17
FEMA Number:
3353
EC Number:
251-532-7
Council of Europe no.:
2153
MDL number:
MFCD00036490
UNSPSC Code:
12164502
PubChem Substance ID:
24901661
Flavis number:
9.240
NACRES:
NA.21

biological source

synthetic

Quality Level

400

grade

FG
Halal
Kosher

Agency

meets purity specifications of JECFA

reg. compliance

EU Regulation 1334/2008 & 178/2002

Assay

≥95%

impurities

<5% cis-3-hexen-1-ol

refractive index

n20/D 1.426 (lit.)

bp

72 °C/40 mmHg (lit.)

application(s)

flavors and fragrances

Documentation

see Safety & Documentation for available documents

food allergen

no known allergens

Organoleptic

green; vegetable

SMILES string

[H]C(=O)OCC\C([H])=C(\[H])CC

InChI

1S/C7H12O2/c1-2-3-4-5-6-9-7-8/h3-4,7H,2,5-6H2,1H3/b4-3-

InChI key

XJHQVZQZUGLZLS-ARJAWSKDSA-N

General description

cis-3-Hexenyl formate is a flavor and fragrance ester mainly used for its green notes. It occurs naturally in gardenia and zinchoge flowers.

Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Warning

Hazard Statements

H226,H315,H319

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

WGK

WGK 2

Flash Point(F)

113.0 °F

Flash Point(C)

45 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Volatile components of Zinchoge flower (Daphne odora Thunb.).
Watanabe I, et al.
Agricultural and Biological Chemistry, 47(3), 483-490 (1983)
Chemical composition of the absolute from gardenia flower.
Hattori R, et al.
Agricultural and Biological Chemistry, 42(7), 1351-1356 (1978)
Flavor Bites: cis-3-Hexenyl Formate: In search of ideal green notes.
Wright J.
Perfumer & Flavorist, 37(7) (2012)
Density and viscosity correlation for several common fragrance and flavor esters.
Djojoputro H & Ismadji S.
Journal of Chemical and Engineering Data, 50(2), 727-731 (2005)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service