T2207
Terephthalaldehyde
ReagentPlus®, 99%
Synonym(s):
Benzene-1,4-dicarboxaldehyde, Terephthaldicarboxaldehyde
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About This Item
Linear Formula:
C6H4(CHO)2
CAS Number:
Molecular Weight:
134.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-784-8
Beilstein/REAXYS Number:
385863
MDL number:
Product Name
Terephthalaldehyde, ReagentPlus®, 99%
InChI key
KUCOHFSKRZZVRO-UHFFFAOYSA-N
InChI
1S/C8H6O2/c9-5-7-1-2-8(6-10)4-3-7/h1-6H
SMILES string
[H]C(=O)c1ccc(cc1)C([H])=O
product line
ReagentPlus®
assay
99%
bp
245-248 °C (lit.)
mp
114-116 °C (lit.)
Quality Level
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Application
Terephthalaldehyde can be used as a starting material for:
- The synthesis of fused bis-benzoquinoline derivatives on reacting with arylamines and cyclic ketones through one pot three component reaction.
- The photochemical synthesis of 5,10-disubstituted[5]helicenes by reacting with benzyl cyanide via Knoevenagel reaction.
- The synthesis of a nitronyl nitroxide (NIT) radical with a pyrimidiniumolate unit, which are useful precursors for building molecular magnets.
Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 1
ppe
Eyeshields, Gloves, type N95 (US)
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Synthesis of dipolar nitronyl nitroxides
Greve S, et al.
Organic Letters, 2(15), 2269-2270 (2000)
Facile photochemical synthesis of 5, 10-disubstituted [5] Helicenes by removing molecular orbital degeneracy
Ito N, et al.
Organic Letters, 16(9), 2502-2505 (2014)
Camphorsulfonic acid catalyzed one-pot three-component reaction for the synthesis of fused quinoline and benzoquinoline derivatives
Gattu R, et al.
The Journal of Organic Chemistry, 82(23), 12416-12429 (2017)
Niklas Keller et al.
Nanoscale, 11(48), 23338-23345 (2019-12-04)
Covalent organic frameworks (COFs), consisting of covalently connected organic building units, combine attractive features such as crystallinity, open porosity and widely tunable physical properties. For optoelectronic applications, the incorporation of heteroatoms into a 2D COF has the potential to yield
Chenyu Lin et al.
BMC chemistry, 14(1), 66-66 (2020-12-10)
For analysis of weak π-π complexes proton-nuclear magnetic resonance (proton-NMR) simultaneously provides information of stacking configurations and association constants [Formula: see text] However, an apparent issue for this approach is inconsistent/impossible constant estimation which often leads to unreasonable interpretation for
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