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Merck
CN

S5012

Sodium hypophosphite monohydrate

≥99%

Synonym(s):

Sodium hypophosphite 1-hydrate, Sodiumphosphinite

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About This Item

Linear Formula:
NaH2PO2 · H2O
CAS Number:
Molecular Weight:
105.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
231-669-9
MDL number:
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Product Name

Sodium hypophosphite monohydrate, ≥99%

InChI key

PLZNPHDJGFDNRM-UHFFFAOYSA-M

InChI

1S/Na.H3O2P.H2O/c;1-3-2;/h;3H2,(H,1,2);1H2/q+1;;/p-1

SMILES string

O.[Na+].[O-][PH2]=O

assay

≥99%

form

powder, crystals or chunks

pH

(6,0 - 8,0 at 50 g/l at 25 °C (77 °F))

solubility

water: 100 mg/mL, clear, colorless

Quality Level

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Application

Sodium hypophosphite monohydrate can be used as a:
  • Reducing agent in the synthesis of nickel nanoparticles (NiNP) from nickel acetate tetrahydrate under microwave irradiation.
  • Hydrogen donor in the enantioselective transfer hydrogenation of aliphatic and aromatic ketones to corresponding alcohols in presence of ruthenium catalyst.
  • Catalyst in esterification of spent grain to improve heavy metal ions adsorption capacity using N,N-dimethylformamide (DMF) as a solvent.

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Fast esterification of spent grain for enhanced heavy metal ions adsorption.
Li Q, et al.
Bioresource Technology, 101(10), 3796-3799 (2010)
Biphasic Glycerol/2-MeTHF, Ruthenium-Catalysed Enantioselective Transfer Hydrogenation of Ketones Using Sodium Hypophosphite as Hydrogen Donor.
Guyon C, et al.
European Journal of Organic Chemistry, 2013(24), 5439-5444 (2013)
Microwave assisted greener synthesis of nickel nanoparticles using sodium hypophosphite.
Eluri R and Paul B
Materials Letters, 76, 36-39 (2012)
C Sánchez-Pedreño et al.
The Analyst, 115(9), 1257-1260 (1990-09-01)
A kinetic method for the determination of Te based on its inhibitory effect on the PdII-catalysed reaction between pyronine G and H2PO2- is described. The influence of experimental variables on the rate of the process and the potential interfering effect
W S Price et al.
Biophysical chemistry, 33(3), 205-215 (1989-07-01)
A 31P-NMR method, which complements earlier 13C-NMR procedures for probing the intra-erythrocyte microenvironment, is described. Hypophosphite is an almost unique probe of the erythrocyte microenvironment, since it is rapidly transported into the cell via the band 3 protein, and intra-

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